Partially fluorinated rare earth metal complexes

被引：15

作者：

Neculai, AM ^{[1
]}

Neculai, D ^{[1
]}

Nikiforov, GB ^{[1
]}

Roesky, HW ^{[1
]}

Schlicker, C ^{[1
]}

Herbst-Irmer, R ^{[1
]}

Magull, J ^{[1
]}

Noltemeyer, M ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 17期

关键词：

lanthanides; fluorides; tin; N donor ligands;

D O I：

10.1002/ejic.200300213

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of LScBr2 (1), LYI2 (3), LHoI2 (4), or LErI2 (5) [L = N,N"-(1,3-dimethyl-1,3-propanediylidene)bis(N',N'-diethyl-1,2-ethanediamine)] with Me3SnF was investigated. Treatment of 1 with Me3SnF results in the formation of (Me3BrSn-mu-F)(2)LSc (2) while compounds 3-5 give [LSnMe2][Me3SnI2] (6) as the only product that could be isolated and characterized. Metathesis reactions of 1 with AgSO3CF3 led to LSc(SO3CF3)(2) (7). Compounds 1, 2, 6 and 7 were characterized by single-crystal X-ray structural analysis. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

引用

页码：3120 / 3126

页数：7

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