Durability and mechanical properties of silane cross-linked wood thermoplastic composites

被引:53
作者
Bengtsson, Magnus
Stark, Nicole M.
Oksman, Kristiina
机构
[1] Norwegian Univ Sci & Technol, Dept Engn Design & Mat, N-7491 Trondheim, Norway
[2] USDA, Forest Prod Lab, US Forest Serv, Madison, WI 53726 USA
[3] Lulea Univ Technol, Div Mfg & Design Wood & Bioanocomposites, Skelleftea, Sweden
关键词
polymer-matrix composites (PMCs); mechanical properties; durability; extrusion; cross-linking;
D O I
10.1016/j.compscitech.2007.02.006
中图分类号
TB33 [复合材料];
学科分类号
摘要
In this study, silane cross-linked wood-polyethylene composite profiles were manufactured by reactive extrusion. These composites were evaluated regarding their durability and mechanical properties in comparison with two non-cross-linked wood-polyethylene composites. An addition of only 2% w/w of silane solution during manufacturing was enough to achieve almost 60% degree of cross-linking after curing. The cross-linked composites showed flexural toughness superior to the non-cross-l inked composites. The cross-linked composites also absorbed less moisture during a boiling test in water and this was an indirect evidence of improved interfacial adhesion. After accelerated weathering for 1000-3000 It the general trend was a decrease in flexural modulus and strength of both the non-cross-linked and cross-linked composites. The decrease in modulus seemed to be lower for the cross-linked composites while the decrease in strength seemed to be higher compared to the non-cross-linked composites. Weathering also resulted in a considerable colour fading of the composites. Water absorption-freeze-thaw cycling decreased the flexural modulus of non-cross-linked composites considerably while there was no statistical decrease in modulus for the cross-linked composites. There was only an insignificant decrease in strength for the composites after the water absorption-freeze-thaw cycling. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2728 / 2738
页数:11
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