Petal-like CoMoO4 Clusters Grown on Carbon Cloth as a Binder-Free Electrode for Supercapacitor Application

被引:38
作者
Chen, Chuanhong [1 ]
Deng, Hangchun [1 ]
Wang, Chongshi [2 ]
Luo, Wenqing [1 ]
Huang, Dejuan [1 ]
Jin, Tianxiang [1 ]
机构
[1] East China Univ Technol, Sch Chem Biol & Mat Sci, Nanchang 330013, Jiangxi, Peoples R China
[2] Drexel Univ, Coll Engn, Dept Civil Architectural & Environm Engn, Philadelphia, PA 19104 USA
基金
中国国家自然科学基金;
关键词
ELECTROCHEMICAL PERFORMANCE; NITROGEN; NANOSTRUCTURES; PHOSPHORUS; NANOSHEETS; NANORODS; NIMOO4;
D O I
10.1021/acsomega.1c02166
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The development of supercapacitors with a high energy density and power density is of great importance for the promotion of energy storage technology. In this study, we designed and prepared petal-like CoMoO4 clusters combined with carbon cloth as an excellent self-standing and binder-free electrode for asymmetric supercapacitors. Due to the abundant electrochemical active sites, the promising electron conduction, and ion diffusion rate, the CoMoO4@carbon cloth (CoMoO4@CC) electrode exhibits an excellent electrochemical performance. The results show that the CoMoO4@CC material exhibits a high specific capacitance (664 F/g at a current density of 1 A/g) and an excellent cycle stability (capacitance remains at 84.0% after 1000 cycles). The assembled symmetrical supercapacitor has an energy density of 27 Wh/kg when the power density is 600 W/kg. Even at a higher power density (6022 W/kg), it still maintains a good energy density (18.4 Wh/kg).
引用
收藏
页码:19616 / 19622
页数:7
相关论文
共 42 条
[1]   Comparison of the Electrochemical Performance of NiMoO4 Nanorods and Hierarchical Nanospheres for Supercapacitor Applications [J].
Cai, Daoping ;
Wang, Dandan ;
Liu, Bin ;
Wang, Yanrong ;
Liu, Yuan ;
Wang, Lingling ;
Li, Han ;
Huang, Hui ;
Li, Qiuhong ;
Wang, Taihong .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (24) :12905-12910
[2]   Hierarchical core/shell structures of ZnO nanorod@CoMoO4 nanoplates used as a high-performance electrode for supercapacitors [J].
Cao, Yunjiu ;
An, Lei ;
Liao, Lijun ;
Liu, Xijian ;
Ji, Tao ;
Zou, Rujia ;
Yang, Jianmao ;
Qin, Zongyi ;
Hu, Junqing .
RSC ADVANCES, 2016, 6 (04) :3020-3024
[3]   Reduced ZnCo2O4@NiMoO4.H2O heterostructure electrodes with modulating oxygen vacancies for enhanced aqueous asymmetric supercapacitors [J].
Chen, Chao ;
Wang, Sha ;
Luo, Xin ;
Gao, Wenjia ;
Huang, Guanjie ;
Zeng, Yan ;
Zhu, Zhihong .
JOURNAL OF POWER SOURCES, 2019, 409 :112-122
[4]   Constructing Nitrogen, Selenium Co-Doped Graphene Aerogel Electrode Materials for Synergistically Enhanced Capacitive Performance [J].
Chen, Jianfa ;
Lin, Chong ;
Zhang, Mengmeng ;
Jin, Tianxiang ;
Qian, Yong .
CHEMELECTROCHEM, 2020, 7 (15) :3311-3318
[5]  
Deng H., ACS OMEGA, V6, P9426
[6]   Facile one-step hydrothermal preparation of molybdenum disulfide/carbon composite for use in supercapacitor [J].
Fan, Le-Qing ;
Liu, Gui-Jing ;
Zhang, Can-Yang ;
Wu, Ji-Huai ;
Wei, Yue-Lin .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (32) :10150-10157
[7]   Construction of hierarchical ZnCo2O4@NixCo2x(OH)6x core/shell nanowire arrays for high-performance supercapacitors [J].
Fu, Wenbin ;
Wang, Yaling ;
Han, Weihua ;
Zhang, Zemin ;
Zha, Heming ;
Xie, Erqing .
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (01) :173-182
[8]   Porous ZnO-Coated Co3O4 Nanorod as a High-Energy-Density Supercapacitor Material [J].
Gao, Miao ;
Wang, Wei-Kang ;
Rong, Qing ;
Jiang, Jun ;
Zhang, Ying-Jie ;
Yu, Han-Qing .
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (27) :23163-23173
[9]   Synthesis, characterization and electrochemical performance of graphene decorated with 1D NiMoO4•nH2O nanorods [J].
Ghosh, Debasis ;
Giri, Soumen ;
Das, Chapal Kumar .
NANOSCALE, 2013, 5 (21) :10428-10437
[10]   Energy storage in electrochemical capacitors: designing functional materials to improve performance [J].
Hall, Peter J. ;
Mirzaeian, Mojtaba ;
Fletcher, S. Isobel ;
Sillars, Fiona B. ;
Rennie, Anthony J. R. ;
Shitta-Bey, Gbolahan O. ;
Wilson, Grant ;
Cruden, Andrew ;
Carter, Rebecca .
ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (09) :1238-1251