Pd-mediated epoxidation of olefins

被引:34
作者
Muzart, Jacques [1 ]
机构
[1] Univ Reims, CNRS, Unite Mixte Rech React Select & Applicat, UFR Sci, F-51687 Reims 2, France
关键词
epoxidation; olefins; palladium; catalysis; stoichiometric reactions;
D O I
10.1016/j.molcata.2007.06.006
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Through the different oxidations of olefins mediated by palladium compounds, the epoxidation has met a limited success. This review summarizes the different stoichiometric and catalytic palladium procedures that led to the production of epoxides from alkenes. The proposed mechanisms are also described with, in some cases, personal comments. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:62 / 72
页数:11
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