Ionothermal synthesis, crystal structure and properties of one organic-inorganic compound based on basket-like {Sr⊂P6Mo18O73} cage

被引：4

作者：

Qin, Zhi-Jie ^{[1
]}

Wang, Yun-Feng ^{[1
]}

Tian, Zheng-Fang ^{[2
]}

Li, Ya-Min ^{[1
]}

An, Bing ^{[1
]}

Bai, Yan ^{[1
]}

Dang, Dong-Bin ^{[1
]}

机构：

[1] Henan Univ, Coll Chem & Chem Engn, Inst Mol & Crystal Engn, Henan Key Lab Polyoxometalate Chem, Kaifeng 475004, Peoples R China

[2] Huanggang Normal Univ, Hubei Key Lab Proc & Applicat Catalyt Mat, Huanggang 438000, Hubei, Peoples R China

来源：

MATERIALS LETTERS | 2019年 / 234卷

基金：

中国国家自然科学基金;

关键词：

Phosphomolybdate; Ionothermal synthesis; Crystal structure; Photocatalytic properties; Electrical properties; IONIC LIQUIDS; POLYOXOMETALATE; DESIGN; UNITS;

D O I：

10.1016/j.matlet.2018.09.135

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

One organic-inorganic hybrid phosphomolybdate compound H(EMIM)(3)[{Cu(phen)(2)}{Sr subset of P6Mo18O73}]center dot H2O (1) (EMIM = 1-ethyl-3-methylimidazolium, phen = 1,10-phenanthroline) has been synthesized and structurally characterized. Compound 1 represents the first example of basket-like {P6Mo18O73} POMs synthesized by ionothermal method, and exhibits a novel structure of the fully oxidized heteropolyanion supported by one {Cu(phen)(2)}(2+) fragment with EMIM cations as charge balancing species. Compound 1 shows an obvious photocatalytic activity for degradation of rhodamine B (RhB). In addition, compound 1 exhibits good multiple electrocatalytic properties toward the redox of H2O2, NaNO2, ascorbic acid (AA) and dopamine hydrochloride (DH), respectively. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：368 / 370

页数：3

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