Catalysis as an important tool of green chemistry

被引:56
作者
Beletskaya, I. P. [1 ]
Kustov, L. M. [2 ]
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
[2] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
关键词
DYNAMIC KINETIC RESOLUTION; CROSS-COUPLING REACTIONS; TRANSITION-METAL-COMPLEXES; TEMPERATURE IONIC LIQUIDS; FINE CHEMICAL-SYNTHESIS; AEROBIC OXIDATION; HECK REACTION; ASYMMETRIC EPOXIDATION; HYDROGEN-PEROXIDE; SECONDARY ALCOHOLS;
D O I
10.1070/RC2010v079n06ABEH004137
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The major advances of the last decade in the catalytic synthesis of organic compounds from the stand-point of the green chemistry principles are surveyed. It is shown that among the most promising approaches to such processes, one should distinguish the use of new catalysts (including nanosized ones) and solvents (water, ionic liquids and fluorous compounds), microwave technologies, super-critical and biphasic media as well a heterogenized catalytic metal complex systems. The major application are as of the metal complex systems comprising hydrogenation, partial oxidation and cross-coupling inlcuding enantioselective reactions are addressed. The bibliography includes 248 references.
引用
收藏
页码:441 / 461
页数:21
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