Hydrogenation/Hydrolytic Ring Opening of 5-HMF by Cp*-Iridium(III) Half-Sandwich Complexes for Bioketones Synthesis

被引：60

作者：

Xu, Zhanwei ^{[1
]}

Yan, Peifang ^{[1
]}

Xu, Wenjuan ^{[1
]}

Liu, Xiumei ^{[1
]}

Xia, Zhi ^{[1
]}

Chung, Benjamin ^{[1
]}

Jia, Songyan ^{[1
]}

Zhang, Z. Conrad ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China

来源：

ACS CATALYSIS | 2015年 / 5卷 / 02期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

homogeneous catalysis; hydrogenation; iridium catalyst; 5-HMF; ketones; CATALYTIC CONVERSION; RENEWABLE RESOURCES; IRIDIUM COMPLEXES; LEVULINIC ACID; BIOMASS; FRUCTOSE; HYDRODEOXYGENATION; HYDROGENOLYSIS; DECOMPOSITION; REDUCTION;

D O I：

10.1021/cs501874v

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new method for one-step synthesis of ketones from biobased 5-hydroxymethylfurfural (5-HMF) and its derivatives is reported. Bipyridine coordinated Cp*-Iridium(III) complexes (Cp*, 1,2,3,4,5-pentamethylcyclopenta-1,3-diene) exhibit highly efficient catalytic performance for hydrogenation/hydrolytic ring opening of 5-HMF and derivatives to produce ketones. The catalytic mechanism is proposed to proceed via carbonyl hydrogenation, hydroxyl group promoted and directed hydrolytic furan ring opening, followed by hydrogenation of a,fi-unsaturated carbonyl compound based on the experimental and independent events' statistical calculation results.

引用

页码：788 / 792

页数：5

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