A novel iron-based catalyst for the biphasic oxidation of benzene to phenol with hydrogen peroxide

被引：6
作者：
Bianchi, D
Bortolo, R
Tassinari, R
Ricci, M
Vignola, R
机构：
[1] EniChem SpA, Ctr Ric Novara, Ist G Donegani, I-28100 Novara, Italy
[2] EniTecnol, I-00016 Monterotondo, Italy
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2000年 / 39卷 / 23期
关键词：
Bipahsic catalysis; Homogenous catalysis; Iron; N ligands; Oxidations;
D O I：
10.1002/1521-3773(20001201)39:23<4321::AID-ANIE4321>3.0.CO;2-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Improved selectivity and decreased formation of overoxygenated byproducts were achieved by using a MeCN/H2O biphasic system for the iron-catalyzed oxidation of benzene to phenol with H2O2. Under optimized reaction conditions with 5-carboxy-2-methylpyrazine-N-oxide as the ligand for iron [Eq. (1)] a benzene conversion of 8.6% and selectivities based on benzene and H2O2 of 97 and 88%, respectively, were obtained.
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页码：4321 / +
页数：4
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