Effect of platinum amount in carbon supported platinum catalyst on performance of polymer electrolyte membrane fuel cell

被引:75
作者
Cho, Yong-Hun
Park, Hyun-Seo
Cho, Yoon-Hwan
Jung, Dae-Sik
Park, Hee-Young
Sung, Yung-Eun [1 ]
机构
[1] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151744, South Korea
[2] Seoul Natl Univ, Res Ctr Energy Convers & Storage, Seoul 151744, South Korea
基金
新加坡国家研究基金会;
关键词
polymer electrolyte membrane fuel cell; catalyst coated membrane; membrane electrode assembly; spray coating; platinum loading;
D O I
10.1016/j.jpowsour.2007.01.067
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The performance of polymer electrolyte membrane fuel cells fabricated with different catalyst loadings (20, 40 and 60 wt.% on a carbon support) was examined. The membrane electrode assembly (MEA) of the catalyst coated membrane (CCM) type was fabricated without a hot-pressing process using a spray coating method with a Pt loading of 0.2mgcm(-2). The surface was examined using scanning electron microscopy. The catalysts with different loadings were characterized by X-ray diffraction and cyclic voltammetry. The single cell performance with the fabricated MEAs was evaluated and electrochemical impedance spectroscopy was used to characterize the fuel cell. The best performance of 742 mA cm(-2) at a cell voltage of 0.6 V was obtained using 40 wt.% Pt/C in both the anode and cathode. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:89 / 93
页数:5
相关论文
共 18 条
[1]   FUEL-CELL TECHNOLOGY AND INNOVATION [J].
APPLEBY, AJ .
JOURNAL OF POWER SOURCES, 1992, 37 (1-2) :223-239
[2]   Novel method for preparation of PEMFC electrodes by the electrospray technique [J].
Benítez, R ;
Soler, J ;
Daza, L .
JOURNAL OF POWER SOURCES, 2005, 151 :108-113
[3]   Nano-composite of PtRu alloy electrocatalyst and electronically conducting polymer for use as the anode in a direct methanol fuel cell [J].
Choi, JH ;
Park, KW ;
Lee, HK ;
Kim, YM ;
Lee, JS ;
Sung, YE .
ELECTROCHIMICA ACTA, 2003, 48 (19) :2781-2789
[4]   Methanol oxidation on Pt/Ru, Pt/Ni, and Pt/Ru/Ni anode electrocatalysts at different temperatures for DMFCs [J].
Choi, JH ;
Park, KW ;
Kwon, BK ;
Sung, YE .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (07) :A973-A978
[5]   PEMFC anode with very low Pt loadings using pulsed laser deposition [J].
Cunningham, N ;
Irissou, E ;
Lefèvre, M ;
Denis, MC ;
Guay, D ;
Dodelet, JP .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (07) :A125-A128
[6]  
DEBE MK, 1999, Patent No. 97948851
[7]  
GASTEIGER HA, 2005, APPL CATAL B-ENVIRON, V59, P10
[8]   High performance proton exchange membrane fuel cells with sputter-deposited Pt layer electrodes [J].
Hirano, S ;
Kim, J ;
Srinivasan, S .
ELECTROCHIMICA ACTA, 1997, 42 (10) :1587-1593
[9]   New RuO2 and carbon-RuO2 composite diffusion layer for use in direct methanol fuel cells [J].
Park, KW ;
Kwon, BK ;
Choi, JH ;
Park, IS ;
Kim, YM ;
Sung, YE .
JOURNAL OF POWER SOURCES, 2002, 109 (02) :439-445
[10]   Investigation of oxygen gain in polymer electrolyte membrane fuel cells [J].
Prasanna, A ;
Ha, HY ;
Cho, EA ;
Hong, SA ;
Oh, IH .
JOURNAL OF POWER SOURCES, 2004, 137 (01) :1-8