Luminescent iron oxide nanoparticles prepared by one-pot aphen-functionalization

被引:9
作者
Govindaiah, Patakamuri [1 ]
Park, Tae-Joon [1 ]
Jung, Yeon Jae [1 ]
Lee, Sun Jong [1 ]
Ryu, Du Yeol [1 ]
Kim, Jung Hyun [1 ]
Cheong, In Woo [2 ]
机构
[1] Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea
[2] Kyungpook Natl Univ, Dept Appl Chem, Taegu 702701, South Korea
关键词
luminescent; iron oxide; inorganic-organic hybrid; aphen-functionalized; nanoparticles; STABILIZED PALLADIUM NANOPARTICLES; MAGNETIC NANOPARTICLES; FLUORESCENT NANOCOMPOSITES; LIGAND-EXCHANGE; SURFACE; HYDROGENATION; NANOCRYSTALS; 1,10-PHENANTHROLINE; POLYMERIZATION; SEMICONDUCTOR;
D O I
10.1007/s13233-010-1107-7
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
5-Amino-1,10-phenanthroline (Aphen)-functionalized monodisperse luminescent iron oxide nanoparticles were prepared using a one-pot synthetic procedure via a thermal decomposition process. Amine functional groups of Aphen as a luminescent source afforded highly stabilized magnetic nanoparticles in polar solvents, resulting in a well-dispersed solution. Transmission electron microscopy (TEM) showed that the size distribution and particle morphology of the iron oxide nanoparticles was improved after anchoring with Aphen. The functionalization of iron oxide nanoparticles with Aphen was examined by UV-vis absorbance and photoluminescence spectroscopy. The Aphen-anchored iron oxide nanoparticles exhibited excellent luminescence properties with an estimated luminescence quantum yield of 0.00354 at room temperature. In addition, these Aphen-anchored iron oxide nanoparticles were characterized by vibrating sample magnetometry (VSM) to reveal the magnetic properties. The Aphenanchored iron oxide nanoparticles exhibited both luminescence and magnetic properties.
引用
收藏
页码:1109 / 1114
页数:6
相关论文
共 53 条
[1]   Magnetic and Temperature-Sensitive Composite Polymer Particles and Adsorption Behavior of Emulsifiers and Trypsin [J].
Ahmad, Hasan ;
Rahman, M. Abdur ;
Miah, M. A. Jalil ;
Tauer, Klaus .
MACROMOLECULAR RESEARCH, 2008, 16 (07) :637-643
[2]   The use of nanocrystals in biological detection [J].
Alivisatos, P .
NATURE BIOTECHNOLOGY, 2004, 22 (01) :47-52
[3]   Synthesis, characterization and electrochemical polymerization of eight transition-metal complexes of 5-amino-1,10-phenanthroline [J].
Bachas, LG ;
Cullen, L ;
Hutchins, RS ;
Scott, DL .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (09) :1571-1577
[4]   Understanding mercapto ligand exchange on the surface of FePt nanoparticles [J].
Bagaria, Hitesh G. ;
Ada, Earl T. ;
Shamsuzzoha, Mohammed ;
Nikles, David E. ;
Johnson, Duane T. .
LANGMUIR, 2006, 22 (18) :7732-7737
[5]   Functionalisation of magnetic nanoparticles for applications in biomedicine [J].
Berry, CC ;
Curtis, ASG .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2003, 36 (13) :R198-R206
[6]   A family of electroluminescent silyl-substituted poly(p-phenylenevinylene)s:: Synthesis, characterization, and structure-property relationships [J].
Chen, ZK ;
Huang, W ;
Wang, LH ;
Kang, ET ;
Chen, BJ ;
Lee, CS ;
Lee, ST .
MACROMOLECULES, 2000, 33 (24) :9015-9025
[7]   PHYSICS OF MAGNETIC FLUIDS [J].
CHIKAZUMI, S ;
TAKETOMI, S ;
UKITA, M ;
MIZUKAMI, M ;
MIYAJIMA, H ;
SETOGAWA, M ;
KURIHARA, Y .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1987, 65 (2-3) :245-251
[8]   Biocompatible heterostructured nanoparticles for multimodal biological detection [J].
Choi, Jin-sil ;
Jun, Young-wook ;
Yeon, Soo-In ;
Kim, Hyoung Chan ;
Shin, Jeon-Soo ;
Cheon, Jinwoo .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (50) :15982-15983
[9]   Fabrication of silica-coated magnetic nanoparticles with highly photoluminescent lanthanide probes [J].
Choi, Jungkweon ;
Kim, Jin Chul ;
Lee, Yong Bok ;
Kim, In Seon ;
Park, Yong Ki ;
Hur, Nam Hwi .
CHEMICAL COMMUNICATIONS, 2007, (16) :1644-1646
[10]   Magnetic-fluorescent nanocomposites for biomedical multitasking [J].
Corr, Serena A. ;
O' Byrne, Aisling ;
Gun'ko, Yurii K. ;
Ghosh, Swapankumar ;
Brougham, Dermot F. ;
Mitchell, Siobhan ;
Volkov, Yuri ;
Prina-Mello, Adriele .
CHEMICAL COMMUNICATIONS, 2006, (43) :4474-4476