Synthesis, optimisation and characterisation of the zeolite NaA using kaolin waste from the Amazon Region. Production of Zeolites KA, MgA and CaA

被引：33

作者：

Maia, Ana Aurea B. ^{[1
]}

Neves, Roberto F. ^{[2
]}

Angelica, Romulo S. ^{[2
]}

Poellmann, Herbert ^{[3
]}

机构：

[1] Fed Univ Para, Fac Ciencias Exatas & Tecnol, BR-68440000 Abaetetuba, Para, Brazil

[2] Fed Univ Para, Programa Pos Grad Geol & Geoquim, BR-66075110 Belem, Para, Brazil

[3] Univ Halle Wittenberg, Inst Geowissenschaften, Mineral, D-06120 Halle, Germany

来源：

APPLIED CLAY SCIENCE | 2015年 / 108卷

关键词：

Waste; Kaolinite; Zeolite A;

D O I：

10.1016/j.clay.2015.02.017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This study aimed to use industrial kaolin waste from the Capim (KC) and Jari (KJ) regions of northern Brazil in the synthesis of the zeolite NaA. A temperature of 110 degrees C was kept constant throughout the synthesis process of the zeolite NaA, and the durations and Na/Al ratios were altered. The results of X-ray diffraction (XRD) analysis showed that high purity zeolite NaA with a high degree of structural order was produced in the following conditions: a Na/Al ratio of 1.64 for KC and KJ and synthesis durations of 18 h for KC and 20 h for KJ. According to the XRD results, which indicated the formation of the zeolites KA, MgA and CaA, the process of cation exchange between the Na from zeolite NaA and the K, Mg and Ca from the solutions was efficient. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：55 / 60

页数：6

共 15 条

[11]

Maia A. A. B., 2007, CERAMICA, P319

[12] SYNTHESIS OF ZEOLITES FROM THERMALLY ACTIVATED KAOLINITE - SOME OBSERVATIONS ON NUCLEATION AND GROWTH [J].

MURAT, M ;

AMOKRANE, A ;

BASTIDE, JP ;

MONTANARO, L .

CLAY MINERALS, 1992, 27 (01) :119-130

[13]

Rabo J.A., 1974, ZEOLITE CHEM CATALYS

[14] A NEW PROCEDURE FOR A ZEOLITE SYNTHESIS FROM NATURAL CLAYS [J].

Rigo, Reus T. ;

Pergher, Sibele B. C. ;

Petkowicz, Diego I. ;

dos Santos, Joao H. Z. .

QUIMICA NOVA, 2009, 32 (01) :21-25

[15] SYNTHESIS OF ZEOLITE NA-A FROM METAKAOLINITE REVISITED [J].

ROCHA, J ;

KLINOWSKI, J ;

ADAMS, JM .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (18) :3091-3097

← 1 2 →