Combining Experiments and Theoretical Calculations to Investigate the Intercalation Behavior of Bis(trifluoromethanesulfonimide) Anion into Graphite Electrodes from Alkyl Phosphates

被引：8
作者：
Zhang, Lei [1 ,2 ]
Wang, Ying [3 ]
Wu, Zhijian [3 ]
Wang, Hongyu [1 ,2 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
[2] Univ Sci & Technol China, Sch Appl Chem & Engn, Hefei 230026, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
来源：
ACS APPLIED MATERIALS & INTERFACES | 2021年 / 13卷 / 29期
基金：
中国国家自然科学基金;
关键词：
alkyl phosphate; solvated anion; concentrated electrolyte solutions; anion intercalation; dual-ion batteries; INITIO MOLECULAR-DYNAMICS; ELECTROCHEMICAL INTERCALATION;
D O I：
10.1021/acsami.1c07222
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
In dual-ion batteries (DIBs) utilizing organic electrolyte solutions, the combinations of electrolyte salt and solvent serve as a determiner of the electrochemical performance of graphite electrode partially because solvent participates in the anion intercalation procedure. In this case, every solvated-anion@graphite intercalation compound possesses the characteristic intercalated gallery height. However, in Li/graphite DIBs with concentrated LiTFSI (lithium bis(trifluoromethanesulfonimide))-alkyl phosphates (ca. trimethyl, triethyl, tripropyl, tributyl phosphate) solutions, solvated-TFSI @graphite intercalation compounds have the nearly identical intercalated gallery height of about 0.803 nm, which may be mainly attributed to both the big size of TFSI - anion and the rigid PO4 framework of these alkyl phosphate solvents.
引用
收藏
页码：34197 / 34201
页数：5
相关论文
共 19 条
[1]   Alternative electrochemical energy storage: potassium-based dual-graphite batteries [J].
Beltrop, K. ;
Beuker, S. ;
Heckmann, A. ;
Winter, M. ;
Placke, T. .
ENERGY & ENVIRONMENTAL SCIENCE, 2017, 10 (10) :2090-2094
[2]   Thermoelectric composites of poly(3-hexylthiophene) and carbon nanotubes with a large power factor [J].
Bounioux, Celine ;
Diaz-Chao, Pablo ;
Campoy-Quiles, Mariano ;
Martin-Gonzalez, Marisol S. ;
Goni, Alejandro R. ;
Yerushalmi-Rozene, Rachel ;
Mueller, Christian .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (03) :918-925
[3]   Towards high-performance dual-graphite batteries using highly concentrated organic electrolytes [J].
Heckmann, Andreas ;
Thienenkamp, Johannes ;
Beltrop, Kolja ;
Winter, Martin ;
Brunklaus, Gunther ;
Placke, Tobias .
ELECTROCHIMICA ACTA, 2018, 260 :514-525
[4]   A Nonflammable Na+-Based Dual-Carbon Battery with Low-Cost, High Voltage, and Long Cycle Life [J].
Jiang, Xiaoyu ;
Liu, Xingwei ;
Zeng, Ziqi ;
Xiao, Lifen ;
Ai, Xinping ;
Yang, Hanxi ;
Cao, Yuliang .
ADVANCED ENERGY MATERIALS, 2018, 8 (36)
[5]   Electrochemical intercalation of bis(fluorosulfonyl)amide anions into graphite from aqueous solutions [J].
Kondo, Yasuyuki ;
Miyahara, Yuto ;
Fukutsuka, Tomokazu ;
Miyazaki, Kohei ;
Abe, Takeshi .
ELECTROCHEMISTRY COMMUNICATIONS, 2019, 100 :26-29
[6]   AB-INITIO MOLECULAR-DYNAMICS SIMULATION OF THE LIQUID-METAL AMORPHOUS-SEMICONDUCTOR TRANSITION IN GERMANIUM [J].
KRESSE, G ;
HAFNER, J .
PHYSICAL REVIEW B, 1994, 49 (20) :14251-14269
[7]   ABINITIO MOLECULAR-DYNAMICS FOR LIQUID-METALS [J].
KRESSE, G ;
HAFNER, J .
PHYSICAL REVIEW B, 1993, 47 (01) :558-561
[8]   A novel aqueous dual-ion battery using concentrated bisalt electrolyte [J].
Li, Huan ;
Kurihara, Takuya ;
Yang, Dengyao ;
Watanabe, Motonori ;
Ishihara, Tatsumi .
ENERGY STORAGE MATERIALS, 2021, 38 :454-461
[9]   Reversible Intercalation of Bis(trifluoromethanesulfonyl)imide Anions from an Ionic Liquid Electrolyte into Graphite for High Performance Dual-Ion Cells [J].
Placke, Tobias ;
Fromm, Olga ;
Lux, Simon Franz ;
Bieker, Peter ;
Rothermel, Sergej ;
Meyer, Hinrich-Wilhelm ;
Passerini, Stefano ;
Winter, Martin .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (11) :A1755-A1765
[10]   A Hybrid Electrolytes Design for Capacity-Equivalent Dual-Graphite Battery with Superior Long-Term Cycle Life [J].
Qiao, Yu ;
Jiang, Kezhu ;
Li, Xiang ;
Deng, Han ;
He, Yibo ;
Chang, Zhi ;
Wu, Shichao ;
Guo, Shaohua ;
Zhou, Haoshen .
ADVANCED ENERGY MATERIALS, 2018, 8 (24)
12