Highly selective synthesis of acetylferrocene by acylation of ferrocene over zeolites

被引：27
作者：
Bejblova, Martina
Zones, Stacey I.
Cejka, Jiri
机构：
[1] Acad Sci Czech Republic, J Heyrovsky Inst Phys Chem, CZ-18223 Prague 8, Czech Republic
[2] Chevron Energy & Technol Co, Richmond, CA 94802 USA
来源：
APPLIED CATALYSIS A-GENERAL | 2007年 / 327卷 / 02期
关键词：
acetylferrocene; acylation; zeolites; structural types;
D O I：
10.1016/j.apcata.2007.05.023
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Zeolites with different structure and concentration of acid sites were investigated in a liquid phase acylation of ferrocene with acetic anhydride. It was found that the conversion of ferrocene increased in the order: medium pore zeolites < 1D large pore zeolites < 3D large pore zeolites. Zeolite SSZ-33 with interconnecting 10 and 12-membered rings exhibited a slightly lower conversion compared with mordenite. The increase in the conversion of ferrocene was observed with decreasing Si/Al ratio for the given zeolite structure. Both Broensted and Lewis acid sites contribute to the catalytic activity of zeolites in ferrocene acylation. Mono-acylated ferrocene (acetylferrocene) was synthesized by this reaction with almost 100% selectivity. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：255 / 260
页数：6
相关论文
共 27 条
  • [1] Molecular modeling studies on zeolite catalysts for shape-selective electrophilic substitution: I acylation of 2-methoxynaphthalene
    Bharathi, P
    Waghmode, SB
    Sivasanker, S
    Vetrivel, R
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1999, 72 (10) : 2161 - 2167
  • [2] Synthesis, structures and reactions of some metallocene alcohols
    Brunker, TJ
    Arisandy, C
    Cowley, AR
    Rees, LH
    Barlow, S
    O'Hare, D
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (01) : 252 - 263
  • [3] Acid-catalyzed synthesis of mono- and dialkyl benzenes over zeolites:: Active sites, zeolite topology, and reaction mechanisms
    Cejka, J
    Wichterlová, B
    [J]. CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2002, 44 (03): : 375 - 421
  • [4] Shape-selective synthesis of 2-acetylnaphthalene via naphthalene acylation with acetic anhydride over large pore zeolites
    Cerveny, L
    Mikulcová, K
    Cejka, J
    [J]. APPLIED CATALYSIS A-GENERAL, 2002, 223 (1-2) : 65 - 72
  • [5] CHOUDARY BM, 2001, Patent No. 6239302
  • [6] Darin VA, 1999, J PRAK CHEM-CHEM ZTG, V341, P588, DOI 10.1002/(SICI)1521-3897(199908)341:6<588::AID-PRAC588>3.3.CO
  • [7] 2-0
  • [8] SOME ACYL FERROCENES AND THEIR REACTIONS
    GRAHAM, PJ
    LINDSEY, RV
    PARSHALL, GW
    PETERSON, ML
    WHITMAN, GM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (13) : 3416 - 3420
  • [9] THE SHAPE-SELECTIVE ACYLATION OF 2-METHOXYNAPHTHALENE, CATALYZED BY ZEOLITES-Y, ZEOLITE-BETA AND ZEOLITE-ZSM-12
    HARVEY, G
    MADER, G
    [J]. COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1992, 57 (04) : 862 - 868
  • [10] Selective mono- and di{(perfluoroalkyl)acylation} of ferrocene
    Hazafy, D
    Sobociková, M
    Stepnicka, P
    Ludvík, J
    Kotora, M
    [J]. JOURNAL OF FLUORINE CHEMISTRY, 2003, 124 (02) : 177 - 181
123