Structure Determination of Neptunium(VI) μ3-Hydroxobenzoate, [(NPO2)2(μ3-OH)2(H5C6COO)2]•2H2O

被引：4
作者：
Charushnikova, Iraida A. [1 ]
Krot, Nikolai N. [1 ]
Makarenkov, Vadim I. [1 ]
机构：
[1] Russian Acad Sci, AN Frumkin Inst Phys Chem & Electrochem, Moscow 119991, Russia
来源：
INORGANIC CHEMISTRY | 2010年 / 49卷 / 17期
关键词：
CRYSTAL-STRUCTURE; BENZOATE; COMPLEXES; PROPERTY; ACID;
D O I：
10.1021/ic100951y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Neptunium(VI) benzoate with mu(3)-OH- has been isolated and studied by the X-ray method. The main structural motive in the crystal is corrugated ribbons [(NpO2)(2)(mu(3)-OH)(2)(C7H5O2)(2)](n) extended along the c axes in which three neptunium pentagonal bipyramids are linked through the mu(3)-OH- ligand. The benzoate ions are arranged at both sides of the ribbons, and each anion binds two adjacent NpO2. The water molecules are arranged in the channels along the c axis.
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页码：7611 / 7613
页数：3
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