Synthesis and Characterization of Carboxyl-terminated Hyperbranched Polyester

被引：1

作者：

Niu, Shi Jie ^{[1
]}

Wang, Jian ^{[1
]}

Bai, Yu Qing ^{[1
]}

Run, Ming Tao ^{[1
]}

机构：

[1] Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China

来源：

MATERIALS SCIENCE AND PROCESSING, ENVIRONMENTAL ENGINEERING AND INFORMATION TECHNOLOGIES | 2014年 / 665卷

关键词：

Hyperbranched Polyester; Carboxyl End-GROUP; Succinic Anhydride; POLYMER;

D O I：

10.4028/www.scientific.net/AMM.665.327

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

In order to prepare carboxyl-terminated hyperbranched polyester(HBP-COOH), succinic anhydride was used to modify hydroxyl-terminated hyperbranched polyester(HBP-OH), and the influences of the solvents, catalysts and time on the product's structure were investigated. When THF is used as the solvent, sodium acetate as the catalyst, the molar ratio of succinic anhydride and hydroxyl groups is 3:1, and the reaction time is 6 h at 65 degrees C, the modification extent of the hydroxyl groups is about 99% with about 95% yield. HBP-COOH has much lower glass transition temperature than that of HBP-OH due to its long and flexible end-groups.

引用

页码：327 / 330

页数：4

共 50 条

[1] Synthesis and scale inhibition performance of carboxyl-terminated hyperbranched polyester
Shan, Ning
Chen, Hualin
Liu, Bailing
Li, Chenying
Meng, Xu
Luo, Rong
Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2015, 31 (01): : 1 - 6
[2] Waterborne carboxyl-terminated hyperbranched oligomer polyester ligand: Synthesis, characterization and chelation with chromium(III)
Yao, Qi
Li, Chenying
Huang, Henghui
Chen, Hualin
Liu, Bailing
JOURNAL OF MOLECULAR STRUCTURE, 2017, 1143 : 371 - 377
[3] Design and Synthesis of Crystalline Carboxyl-terminated Polyester Resin
Ye, Xiufang
Lin, Jingxuan
Chen, Dongchu
Chang, Menglei
Wei, Hongyang
MATERIALS SCIENCE-MEDZIAGOTYRA, 2021, 27 (02): : 217 - 223
[4] Doxorubicin-Loaded Hybrid Micelles Based on Carboxyl-Terminated Hyperbranched Polyester Polyol
Khannanov, Artur
Rossova, Anastasia
Ulakhovich, Nikolay
Evtugyn, Vladimir
Valiullin, Lenar
Nabatov, Alexey
Kutyrev, Gennadiy
Kutyreva, Marianna
ACS APPLIED POLYMER MATERIALS, 2022, 4 (04): : 2553 - 2561
[5] Synthesis and Characterization of a Carboxyl-Terminated Waterborne Hyperbranched Polymer and Its Coordination Behavior with Chromium(III)
Li, Chenying
Chen, Hualin
Liu, Bailing
Wang, Bin
Luo, Rong
Shan, Ning
JOURNAL OF APPLIED POLYMER SCIENCE, 2014, 131 (08)
[6] Synthesis, Characterization, Curing and Properties of Carboxyl-Terminated Liquid Fluoropolymers
Li, Juan
Lu, Yafei
Liu, Yu
Li, Yun
Zhang, Xiaoa
Qi, Shicheng
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2014, 53 (01) : 46 - 53
[7] Novel and simple synthesis of carboxyl-terminated polyisobutylenes
Nagy, M
Kéki, S
Orosz, LS
Deák, G
Herczegh, P
Lévai, A
Zsuga, M
MACROMOLECULES, 2005, 38 (10) : 4043 - 4046
[8] Simultaneous enhancements in toughness, tensile strength, and thermal properties of epoxy-anhydride thermosets with a carboxyl-terminated hyperbranched polyester
Fei, Xiaoma
Wei, Wei
Tang, Yuyao
Zhu, Ye
Luo, Jing
Chen, Mingqing
Liu, Xiaoya
EUROPEAN POLYMER JOURNAL, 2017, 90 : 431 - 441
[9] PH-responsive self-assembly of carboxyl-terminated hyperbranched polymers
Dong, Wenyong
Zhou, Yongfeng
Yan, Deyue
Li, Huiqin
Liu, Yu
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (10) : 1255 - 1262
[10] Synthesis and Characterization of Carboxyl-terminated Polyethylene Glycol Functionalized Mesoporous Silica Nanoparticles
Wang Yu
Wang Youyun
Wang Wanxia
Zhu Hongda
Liu Mingxing
JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 2018, 33 (06): : 1540 - 1545

← 1 2 3 4 5 →