Synthesis and characterization of new Schiff bases and their cobalt(II), nickel(II), copper(II), zinc(II), cadmium(II) and mercury(II) complexes

被引：30

作者：

Uçan, SY ^{[1
]}

Uçan, M

Mercimek, B

机构：

[1] Nigde Univ, Fac Arts & Sci, Dept Chem, TR-51200 Nigde, Turkey

[2] Selcuk Univ, Fac Educ, Dept Chem, Konya, Turkey

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2005年 / 35卷 / 05期

关键词：

Schiff base ligands; spectra; transition metal complexes;

D O I：

10.1081/SIM-200059233

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nickel(II), copper( II), cobalt( II), zinc( II), cadmium( II) and mercury( II) complexes chelates containing the Schiff base ligands methyliminoisonitroso-2-acetylnaphthalene (HL1) and benzyliminoisonitroso-2-acetylnaphthalene (HL2) have been prepared. The results suggest that the Schiff bases function as bidentate ligands and indicate a mononuclear structure for the Cu(II) complexes with square-planar geometry. The Ni(II), Zn(II), Hg(II) and Cd(II) complexes are of tetrahedral geometry and the Co(II) complexes with octahedral geometry with water molecules at the axial positions. These compounds have been characterized by elemental analyses, magnetic susceptibility, mass, IR, UV, H-1 and C-13 NMR spectroscopy.

引用

页码：417 / 421

页数：5

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