Study of different kinetic models for oil shale pyrolysis

被引：77

作者：

Li, SY ^{[1
]}

Yue, CT ^{[1
]}

机构：

[1] Univ Petr, Sch Chem Engn, State Key Lab Heavy Oil Proc, Beijing 102200, Peoples R China

来源：

FUEL PROCESSING TECHNOLOGY | 2004年 / 85卷 / 01期

基金：

中国国家自然科学基金;

关键词：

pyrolysis; oil shale; TGA; kinetics;

D O I：

10.1016/S0378-3820(03)00097-3

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Pyrolysis experiments on oil shale samples from Fushun and Maoming were carried out using a thermogravimetric analyzer (TGA) at four different heating rates of 1, 2, 5 and 10degreesC/min. The kinetic parameters of oil shale pyrolysis were determined from TGA data by using integral method, differential method, Friedman procedure, maximum rate method and parallel first order reaction model. The different methods and the kinetic parameters thus obtained are discussed and compared with each other. (C) 2003 Published by Elsevier B.V.

引用

页码：51 / 61

页数：11

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