Modeling and optimization of oxide copper cementation kinetics

被引:5
作者
Shahrivar, Ebrahim [1 ]
Karamoozian, Mohammad [1 ]
Gharabaghi, Mandi [2 ]
机构
[1] Shahrood Univ Technol, Fac Min Petr & Geophys Engn, Shahrood, Iran
[2] Univ Tehran, Fac Min Engn, Tehran, Iran
来源
SN APPLIED SCIENCES | 2020年 / 2卷 / 03期
关键词
Cementation; Kinetics; Design of experiments; Optimization; Modeling; DISSOLUTION KINETICS; MALACHITE; RECOVERY; IRON; ORE; ZINC;
D O I
10.1007/s42452-020-2247-9
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
In this paper, the parameters affecting the process of copper cementation, its optimization and kinetic investigation are studied. For this purpose, the main parameters, such as pH, copper concentrations, stirring speed, reaction time and the kinetics of the cementation process have been investigated by using the experimental design method. The results show that the three parameters of reaction time, stirring speed and copper concentrations, have the most effect on the copper cementation process, respectively.The experimental kinetic results showed that the reaction time and stirring speed have the most effect on the cementation kinetics, respectively. Also, the stirring speed -time interaction had the most effect on the cementation kinetics. Finally, the optimum conditions for cementation were 10 min time, copper concentration 3 g/I, pH= 1 and stirring speed of 500 RPM, that in the optimal conditions for cementation recovery was about 90% and the results showed that the recovery obtained from the experiments and the predicted recovery were in good agreement.
引用
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页数:13
相关论文
共 18 条
[1]  
AGRAWAL RD, 1982, J S AFR I MIN METALL, V82, P106
[2]   Copper recovery improvement in an industrial flotation circuit: A case study of Sarcheshmeh copper mine [J].
Asghari, Mehrshad ;
Nakhaei, Fardis ;
VandGhorbany, Omid .
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2019, 41 (06) :761-778
[3]   Dissolution kinetics of malachite in sulphuric acid [J].
Bingöl, D ;
Canbazoglu, M .
HYDROMETALLURGY, 2004, 72 (1-2) :159-165
[4]   Copper recovery from ore by liquid-liquid extraction using aqueous two-phase system [J].
de Lemos, Leandro Rodrigues ;
Boggione Santos, Igor Jose ;
Rodrigues, Guilherme Dias ;
Mendes da Silva, Luis Henrique ;
Hespanhol da Silva, Maria C. .
JOURNAL OF HAZARDOUS MATERIALS, 2012, 237 :209-214
[5]   A kinetic study of copper cementation with zinc in aqueous solutions [J].
Demirkiran, Nizamettin ;
Ekmekyapar, Ahmet ;
Kunkul, Asim ;
Baysar, Ahmet .
INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 2007, 82 (02) :80-85
[6]   Copper cementation on zinc and iron mixtures: Part 2: Fluidized bed configuration [J].
Gros, F. ;
Baup, S. ;
Aurousseau, M. .
HYDROMETALLURGY, 2011, 106 (1-2) :119-126
[7]  
Irannegade M, 2009, KINETICS AMIRKABIR S, V20, P63
[8]   Kinetics and deposit morphology of copper cementation onto zinc, iron and aluminium [J].
Karavasteva, M .
HYDROMETALLURGY, 2005, 76 (1-2) :149-152
[9]  
Kiraz E, 2014, THESIS
[10]   Dissolution of copper and iron from malachite ore and precipitation of copper sulfate pentahydrate by chemical process [J].
Kokes, H. ;
Morcali, M. H. ;
Acma, E. .
ENGINEERING SCIENCE AND TECHNOLOGY-AN INTERNATIONAL JOURNAL-JESTECH, 2014, 17 (01) :39-44