New fluoroalkenes and alcohol with pentafluoro-λ6-sulfanyl (SF5) terminal groupings

被引：11

作者：

Nixon, PG ^{[1
]}

Renn, J ^{[1
]}

Terjeson, RJ ^{[1
]}

Choi, YS ^{[1
]}

Winter, R ^{[1
]}

Gard, GL ^{[1
]}

机构：

[1] Portland State Univ, Dept Chem, Portland, OR 97207 USA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1998年 / 91卷 / 01期

基金：

美国国家科学基金会;

关键词：

pentafluorosulfanyl; alkene; alcohol; synthesis; NMR spectroscopy; mass spectrometry;

D O I：

10.1016/S0022-1139(98)00191-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of new compounds that contain both a terminal pentafluoro-lambda(6)-sulfanyl (SF5) group and an alkene or alcohol functional group is reported. Five new SF5 containing alkenes and one new SF5 containing alcohol were prepared: SF5CH2CHBrCH2CF=CF2 (1), SF5CF2CF2CH2CHICH2CF=CF2 (2), SF5CF2CF2CH2CH2CH2CF=CF2 (3), SF5CF2CF2CH=CH2 (4), SF5(CF2CF2)(2)CH=CH2 (5) and SF5CF2CF2CH2CH2OH (6). These compounds are useful as monomers or as intermediates in the preparation of polymers, polymer surface coatings, and surfactants. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：13 / 18

页数：6

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