Synchrotron X-ray study of [5,15-diphenyl-2,8,12,18-tetra-n-hexyl-3,7,13,17-tetramethylporphyrinato]nickel(II)

被引：2
作者：
Bond, AD
Feeder, N
Redman, JE
Teat, SJ
Sanders, JKM
机构：
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
[2] CLRC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷
关键词：
D O I：
10.1107/S1600536803018853
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title compound, [Ni(C60H76N4)], has been determined at 150 K by a synchrotron single-crystal X-ray diffraction study. The asymmetric unit contains two independent molecules of the porphyrinatonickel complex which display distorted saddle conformations. The porphyrins are arranged into layers, with the n-hexyl substituents extending above and below the plane of these layers, and interdigitating between them.
引用
收藏
页码：M818 / M820
页数：3
相关论文
共 7 条
  • [1] ENZYME MIMICS BASED ON CYCLIC PORPHYRIN OLIGOMERS - STRATEGY, DESIGN AND EXPLORATORY SYNTHESIS
    ANDERSON, HL
    SANDERS, JKM
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1995, (18): : 2223 - 2229
  • [2] Molecular conformation and intermolecular interactions in the crystal structures of free-base 5,15-diarylporphyrins
    Bond, AD
    Feeder, N
    Redman, JE
    Teat, SJ
    Sanders, JKM
    [J]. CRYSTAL GROWTH & DESIGN, 2002, 2 (01) : 27 - 39
  • [3] CLEGG W, 1995, LSCELL
  • [4] Comparative analysis of the conformations of symmetrically and asymmetrically deca- and undecasubstituted porphyrins bearing meso-alkyl or -aryl groups
    Senge, MO
    Medforth, CJ
    Forsyth, TP
    Lee, DA
    Olmstead, MM
    Jentzen, W
    Pandey, RK
    Shelnutt, JA
    Smith, KM
    [J]. INORGANIC CHEMISTRY, 1997, 36 (06) : 1149 - 1163
  • [5] Sheldrick G.M., 1996, SADABS VERSION 2008
  • [6] SHELDRICK GM, 2000, SHELXTL VERS 6 10
  • [7] *SIEM AN XRAY INST, 1994, SMART VERS 4 SAINT V
1