VAPOR-LIQUID EQUILIBRIUM CALCULATION FOR SIMULATION OF BIOETHANOL CONCENTRATION FROM SUGARCANE

被引：7

作者：

Matugi, Karina ^{[1
]}

Chiavone-Filho, Osvaldo ^{[2
]}

de Arruda Ribeiro, Marcelo Perencin ^{[1
]}

Soares, Rafael de Pelegrini ^{[3
]}

Giordano, Roberto de Campos ^{[1
]}

机构：

[1] Univ Fed Sao Carlos, Programa Posgrad Engn Quim, Rodovia Washington Luiz,Km 235 S-N, BR-13565905 Sao Carlos, SP, Brazil

[2] Univ Fed Rio Grande do Norte, Dept Engn Quim, Av Senador Salgado Filho S-N, BR-59066800 Natal, RN, Brazil

[3] Univ Fed Rio Grande do Sul, Escola Engn, Dept Engn Quim, Rua Engenheiro Luis Englert S-N, BR-90040040 Porto Alegre, RS, Brazil

来源：

BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING | 2018年 / 35卷 / 02期

关键词：

vapor-liquid equilibrium in ethanol production; vapor pressure; Poynting factor; fugacity coefficient; F-SAC; MODIFIED UNIFAC MODEL; BINARY-MIXTURES; DISTILLATION; ETHANOL; PREDICTION; DEHYDRATION; ENTRAINER; PRESSURE; SYSTEMS; SOLVENT;

D O I：

10.1590/0104-6632.20180352s20160278

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The robustness of the simulation of bioethanol concentration from sugarcane faces two major challenges: the presence of several minor components and the nonlinear behavior of vapor-liquid equilibrium (VLE) calculations. This work assesses the effect of simplifications to overcome these difficulties. From a set of seventeen substances, methanol, n-propanol, isobutanol, 2-methyl-1-butanol and 3-methyl-1-butanol were selected through the examination of the influence of each minor component on vapor-liquid equilibrium calculations of ethanol-water-third component systems. The selection procedure was based on Txy diagrams built using the modified Raoult's law. The influence of the ratio between the vapor phase fugacity coefficients and of the Poynting correction factor were verified. The accuracy of four correlations for vapor pressure was evaluated, and two functional-group activity coefficient models were scrutinized: the recent Functional-Segment Activity Coefficient (F-SAC) and the UNIFAC-Do model.

引用

页码：341 / 352

页数：12

共 50 条

[1] CALCULATION OF VAPOR-LIQUID EQUILIBRIUM DATA FROM EXCESS THERMODYNAMIC PROPERTIES
郑炽
英徐根
汤沛民
Chinese Journal of Chemical Engineering, 1982, (00) : 91 - 97
[2] AZEOTROPE BEHAVIOR AND VAPOR-LIQUID EQUILIBRIUM CALCULATION.
Wisniak, Jaime
AIChEMI Modular Instruction, Series D: Thermodynamics, 1982, 3 : 17 - 23
[3] CALCULATION OF VAPOR-LIQUID AND LIQUID-LIQUID EQUILIBRIUM BY AN EQUATION OF STATE
KOLASINSKA, G
MOORWOOD, RAS
WENZEL, H
FLUID PHASE EQUILIBRIA, 1983, 13 (OCT) : 121 - 132
[4] NEW ANALOG CIRCUIT FOR CALCULATION AND SIMULATION OF VAPOR-LIQUID EQUILIBRIUM OF BINARY-MIXTURES
OCON, J
GOTOR, AG
ANALES DE QUIMICA-INTERNATIONAL EDITION, 1973, 69 (03): : 397 - 403
[5] Simulation and calculation of vapor-liquid equilibrium of acetic acid light-ends column
Process Division, China Hualu Engineering and Technology Co. Ltd., Xi'an 710054, China
Huaxue Gongcheng, 2008, 10 (52-54):
[6] VAPOR-LIQUID EQUILIBRIUM - NEW STILL AND METHOD FOR DETERMINING VAPOR-LIQUID EQUILIBRIUM
HARPER, BG
MOORE, JC
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1957, 49 (03): : 411 - 414
[7] CALCULATION OF VAPOR-LIQUID EQUILIBRIUM OF MIXTURES FROM VAPOR PRESSURE EQUATION OF PURE COMPONENTS.
Liang, Limin
Hou, Yujun
Huagong Xuebao/Journal of Chemical Industry and Engineering (China), 1986, 2 (03): : 342 - 350
[8] Calculation of vapor-liquid equilibrium by linear and nonlinear statistical theory
Beijing Huagong Daxue Xuebao, 2 (22-26):
[9] VAPOR-LIQUID EQUILIBRIUM WITH ASSOCIATION IN VAPOR
SCHMIDT, A
GREWER, T
CHEMIE INGENIEUR TECHNIK, 1973, 45 (06) : 728 - 728
[10] Vapor-liquid equilibrium calculation of the system water-nitric acid over the entire concentration range
Brandani, S
Brandani, V
FLUID PHASE EQUILIBRIA, 1996, 114 (1-2) : 37 - 45

← 1 2 3 4 5 →