Determination of pyrethroid insecticides in environmental samples

被引：109

作者：

Feo, M. L. ^{[1
]}

Eljarrat, E. ^{[1
]}

Barcelo, D. ^{[1
,2
]}

机构：

[1] CSIC, IDAEA, Dept Environm Chem, ES-08034 Barcelona, Spain

[2] Univ Girona, Catalan Inst Water Res ICRA, Girona 17003, Spain

来源：

TRAC-TRENDS IN ANALYTICAL CHEMISTRY | 2010年 / 29卷 / 07期

关键词：

Comprehensive two-dimensional gas chromatography; Electron-capture detection; Enantiomeric separation; Environmental analysis; Gas chromatography; Liquid chromatography; Mass spectrometry; Pyrethroid; Tandem mass spectrometry; Time-of-flight mass spectrometry; SOLID-PHASE MICROEXTRACTION; BAR SORPTIVE EXTRACTION; GAS-CHROMATOGRAPHY; PULSED SPLITLESS; ORGANOPHOSPHORUS PESTICIDES; SYNTHETIC PYRETHROIDS; LIQUID-CHROMATOGRAPHY; MULTIRESIDUE ANALYSIS; BIOLOGICAL-ACTIVITY; THERMAL-DESORPTION;

D O I：

10.1016/j.trac.2010.03.011

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Pyrethroids are synthesized derivates of pyrethrins, which are extremely toxic for aquatic life and possible human carcinogens. After the ban on some organophosphorus insecticides, applications of pyrethroid insecticides increased sharply. In this article, we discuss different aspects of current analytical methodology, such as sample preparation, extraction, purification and final determination. Most pyrethroid analyses are performed by gas chromatography (GC) coupled to electron-capture detection or mass spectrometry (MS), although there are options based on tandem MS (MS') or comprehensive two-dimensional GC (GC x GC) coupled to time-of-flight MS (ToF-MS). We discuss the advantages and the disadvantages of the different instrumental techniques. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：692 / 705

页数：14

共 73 条

[41] CHEMICAL AND PHOTOCHEMICAL ISOMERIZATION OF DELTAMETHRIN [J].

MAGUIRE, RJ .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1990, 38 (07) :1613-1617

[42] Development of a class selective immunoassay for the type II pyrethroid insecticides [J].

Mak, SK ;

Shan, G ;

Lee, HJ ;

Watanabe, T ;

Stoutamire, DW ;

Gee, SJ ;

Hammock, BD .

ANALYTICA CHIMICA ACTA, 2005, 534 (01) :109-120

[43]

Maund SJ, 2002, ENVIRON TOXICOL CHEM, V21, P9, DOI [10.1897/1551-5028(2002)021<0009:PBATOT>2.0.CO

[44]

2, 10.1002/etc.5620210102]

[45] Extraction and analysis methods for the determination of pyrethroid insecticides in surface water, sediments and biological tissues at environmentally relevant concentrations [J].

Mekebri, A. ;

Crane, D. B. ;

Blondina, G. J. ;

Oros, D. R. ;

Rocca, J. L. .

BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY, 2008, 80 (05) :455-460

[46]

*MIN HLTH LAB WELF, 2003, AN METH TARG CHEM WA

[47] Isolation and identification of the metolachlor stereoisomers using high-performance liquid chromatography, polarimetric measurements, and enantioselective gas chromatography [J].

Müller, MD ;

Poiger, T ;

Buser, HR .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2001, 49 (01) :42-49

[48] Sequential stir bar sorptive extraction for uniform enrichment of trace amounts of organic pollutants in water samples [J].

Ochiai, Nobuo ;

Sasamoto, Kikuo ;

Kanda, Hirooki ;

Pfannkoch, Edward .

JOURNAL OF CHROMATOGRAPHY A, 2008, 1200 (01) :72-79

[49] Fast screening of pesticide multiresidues in aqueous samples by dual stir bar sorptive extraction-thermal desorption-low thermal mass gas chromatography-mass spectrometry [J].

Ochiai, Nobuo ;

Sasamoto, Kikuo ;

Kanda, Hirooki ;

Nakamura, Sadao .

JOURNAL OF CHROMATOGRAPHY A, 2006, 1130 (01) :83-90

[50] A liquid chromatography-tandem mass spectrometry multiresidue method for quantification of specific metabolites of organophosphorus pesticides, synthetic pyrethroids, selected herbicides, and DEET in human urine [J].

Olsson, AO ;

Baker, SE ;

Nguyen, JV ;

Romanoff, LC ;

Udunka, SO ;

Walker, RD ;

Flemmen, KL ;

Barr, DB .

ANALYTICAL CHEMISTRY, 2004, 76 (09) :2453-2461

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