Determination of pyrethroid insecticides in environmental samples

被引：109
作者：
Feo, M. L. [1 ]
Eljarrat, E. [1 ]
Barcelo, D. [1 ,2 ]
机构：
[1] CSIC, IDAEA, Dept Environm Chem, ES-08034 Barcelona, Spain
[2] Univ Girona, Catalan Inst Water Res ICRA, Girona 17003, Spain
来源：
TRAC-TRENDS IN ANALYTICAL CHEMISTRY | 2010年 / 29卷 / 07期
关键词：
Comprehensive two-dimensional gas chromatography; Electron-capture detection; Enantiomeric separation; Environmental analysis; Gas chromatography; Liquid chromatography; Mass spectrometry; Pyrethroid; Tandem mass spectrometry; Time-of-flight mass spectrometry; SOLID-PHASE MICROEXTRACTION; BAR SORPTIVE EXTRACTION; GAS-CHROMATOGRAPHY; PULSED SPLITLESS; ORGANOPHOSPHORUS PESTICIDES; SYNTHETIC PYRETHROIDS; LIQUID-CHROMATOGRAPHY; MULTIRESIDUE ANALYSIS; BIOLOGICAL-ACTIVITY; THERMAL-DESORPTION;
D O I：
10.1016/j.trac.2010.03.011
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Pyrethroids are synthesized derivates of pyrethrins, which are extremely toxic for aquatic life and possible human carcinogens. After the ban on some organophosphorus insecticides, applications of pyrethroid insecticides increased sharply. In this article, we discuss different aspects of current analytical methodology, such as sample preparation, extraction, purification and final determination. Most pyrethroid analyses are performed by gas chromatography (GC) coupled to electron-capture detection or mass spectrometry (MS), although there are options based on tandem MS (MS') or comprehensive two-dimensional GC (GC x GC) coupled to time-of-flight MS (ToF-MS). We discuss the advantages and the disadvantages of the different instrumental techniques. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：692 / 705
页数：14
相关论文
共 73 条
  • [1] Aaron J-J, 1993, MOL LUMINESCENCE SPE, P85
  • [2] ALI I, 2004, CHIRAL POLLUTANTS
  • [3] Use and toxicity of pyrethroid pesticides in the Central Valley, California, USA
    Amweg, EL
    Weston, DP
    Ureda, NM
    [J]. ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY, 2005, 24 (04) : 966 - 972
  • [4] [Anonymous], ECOTOX US GUID ECOTO
  • [5] [Anonymous], 2006, REREGISTRATION ELIGI
  • [6] SOLID-PHASE MICROEXTRACTION WITH THERMAL-DESORPTION USING FUSED-SILICA OPTICAL FIBERS
    ARTHUR, CL
    PAWLISZYN, J
    [J]. ANALYTICAL CHEMISTRY, 1990, 62 (19) : 2145 - 2148
  • [7] [ATSDR] Agency for Toxic Substances and Disease Registry, 2003, TOX PROF PYR PYR, P30333
  • [8] Thermal behaviour and biological activity of pyrethroids in smoke-generating formulations
    Audino, PG
    de Licastro, SA
    Zerba, E
    [J]. PESTICIDE SCIENCE, 1999, 55 (12): : 1187 - 1193
  • [9] BALLUSSEN E, 2002, ANAL BIOANAL CHEM, V373, P3
  • [10] Optimization of separation and detection conditions for the multiresidue analysis of pesticides in grapes by comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry
    Banerjee, Kaushik
    Patil, Sangram H.
    Dasgupta, Soma
    Oulkar, Dasharath P.
    Patil, Shubhangi B.
    Savant, Rahul
    Adsule, Pandurang G.
    [J]. JOURNAL OF CHROMATOGRAPHY A, 2008, 1190 (1-2) : 350 - 357
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