White Electroluminescence from a Single-Polymer System with Simultaneous Three-color Emission

被引：2
作者：
Xu, Yang [1 ,2 ]
Wang, Hua [1 ,2 ]
Song, Chunli [1 ,2 ]
Liu, Xuguang [1 ]
Xu, Bingshe [1 ,2 ]
机构：
[1] Taiyuan Univ Technol, Minist Educ, Key Lab Interface Sci & Engn Adv Mat, Taiyuan 030024, Peoples R China
[2] Taiyuan Univ Technol, Res Ctr Adv Mat Sci & Technol, Taiyuan 030024, Peoples R China
来源：
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2012年 / 22卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Fluorene; Fluorenone; White light; Polymer; LIGHT-EMITTING-DIODES; FLUORENE-BASED COPOLYMERS; POLYFLUORENE COPOLYMERS; IRIDIUM COMPLEX; GREEN EMISSION; PHENOTHIAZINE; BLUE; PHOTOLUMINESCENCE; DERIVATIVES; DEVICES;
D O I：
10.1007/s10904-011-9585-4
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of polymers were synthesized by incorporating low contents of fluorenone (FO) and 4,7-bis(2-thienyl)-2,1,3-benzothiadiazole (DBT) into the main chain of poly(9,9-dioctylfluorene). White-light emission was obtained from a single polymer by adjusting the FO and DBT contents. All polymers showed good thermal stability with 5% weight loss up to 410 degrees C and good solubility in common organic solvents. Electroluminescence devices with indium tin oxide/poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate)/emission layer/Ca/Al structure were found to emit white light with Commission Internationale de l'Eclairage coordinate of (0.37, 0.34). These devices exhibited a maxium brightness of 3414 cd/m(2) and a maximum current efficiency of 2.79 cd/A.
引用
收藏
页码：76 / 81
页数：6
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  • [1] Saturated and efficient red light-emitting fluorene-based alternating polymers containing phenothiazine derivatives
    Cho, NS
    Park, JH
    Lee, SK
    Lee, J
    Shim, HK
    Park, MJ
    Hwang, DH
    Jung, BJ
    [J]. MACROMOLECULES, 2006, 39 (01) : 177 - 183
  • [2] White organic light-emitting devices for solid-state lighting
    D'Andrade, BW
    Forrest, SR
    [J]. ADVANCED MATERIALS, 2004, 16 (18) : 1585 - 1595
  • [3] Intramolecular fluorescence quenching in luminescent copolymers containing fluorenone and fluorene units: A direct measurement of intrachain exciton hopping rate
    Dias, FB
    Maiti, M
    Hintschich, SI
    Monkman, AP
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2005, 122 (05)
  • [4] White electrophosphorescence from semiconducting polymer blends
    Gong, X
    Ma, WL
    Ostrowski, JC
    Bazan, GC
    Moses, D
    Heeger, AJ
    [J]. ADVANCED MATERIALS, 2004, 16 (07) : 615 - +
  • [5] Stabilized blue emission from polyfluorene-based light-emitting diodes: Elimination of fluorenone defects
    Gong, XO
    Iyer, PK
    Moses, D
    Bazan, GC
    Heeger, AJ
    Xiao, SS
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (04) : 325 - 330
  • [6] Novel red-emitting fluorene-based copolymers
    Hou, Q
    Xu, YS
    Yang, W
    Yuan, M
    Peng, JB
    Cao, Y
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (10) : 2887 - 2892
  • [7] Achieving high-efficiency polymer white-light-emitting devices
    Huang, JS
    Li, G
    Wu, E
    Xu, QF
    Yang, Y
    [J]. ADVANCED MATERIALS, 2006, 18 (01) : 114 - 117
  • [8] White LEDs using conjugated polymer blends
    Hwang, DH
    Park, MJ
    Lee, C
    [J]. SYNTHETIC METALS, 2005, 152 (1-3) : 205 - 208
  • [9] Synthesis and Characterization of Indeno[1,2-b]fluorene-Based White Light-Emitting Copolymer
    Jeong, Eunjae
    Kim, Sun Hee
    Jung, In Hwan
    Xia, Yangjun
    Lee, Kwanghee
    Suh, Hongsuk
    Shim, Hong-Ku
    Woo, Han Young
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (14) : 3467 - 3479
  • [10] Polyfluorene terpolymers containing phenothiazine and fluorenone: Effects of donor and acceptor moieties on energy and intrachain charge transfer processes in the photoluminescence and electroluminescence of multichromophore copolymers
    Kulkarni, Abhishek P.
    Kong, Xiangxing
    Jenekhe, Samson A.
    [J]. MACROMOLECULES, 2006, 39 (25) : 8699 - 8711
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