Dendrite-like Co3O4 nanostructure and its applications in sensors, supercapacitors and catalysis

被引:122
作者
Pang, Huan [1 ,2 ]
Gao, Feng [1 ]
Chen, Qun [1 ]
Liu, Rongmei [1 ,2 ,3 ]
Lu, Qingyi [2 ]
机构
[1] Nanjing Univ, Dept Mat Sci & Engn, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing Natl Lab Microstruct,Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China
[3] Anhui Polytech Univ, Coll Biol & Chem Engn, Wuhu 241000, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
DIRECT ELECTROCHEMISTRY; HYDROGEN-PEROXIDE; COBALT OXIDE; ELECTRODE; CALCINATION; NANOTUBES; NANORODS; FILM;
D O I
10.1039/c2dt12494g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Dendrite-like Co3O4 nanostructure, made up of many nanorods with diameters of 15-20 nm and lengths of 2-3 mu m, has been successfully prepared by calcining the corresponding nanostructured Co-8-hydroxyquinoline coordination precursor in air. The Co3O4 nanostructure was evaluated as an electrochemical sensor for H2O2 detection and the results reveal that it has good linear dependence and high sensitivity to H2O2 concentration changes. As an electrode material of a supercapacitor, it was found that the nanostructured Co3O4 electrode exhibits high specific capacitance and long cycle life. The Co3O4 nanostructure also has good catalytic properties and is steadily active for CO oxidation, giving 100% CO conversion at low temperatures. The multifunctional Co3O4 nanostructure would be a promising functional nanomaterial applied in multi industrialized fields.
引用
收藏
页码:5862 / 5868
页数:7
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