Activity of titanium in Fe-Cr melts

被引：16
|
作者：
Choi, HY
Slye, WE
Fruehan, RJ [1 ]
Nunnington, RC
机构：
[1] Pohang Iron & Steel Co Ltd, Pohang, Kyungbuk, South Korea
[2] Carnegie Mellon Univ, Dept Mat Sci & Engn, Pittsburgh, PA 15213 USA
[3] Praxair Inc, Ind Applicat R&D Primary Met & Met Fabricat, Tonawanda, NY 14150 USA
[4] LWB Refractories, York, PA 17405 USA
来源：
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE | 2005年 / 36卷 / 04期
关键词：
D O I：
10.1007/s11663-005-0045-9
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The activity of titanium in Fe-Cr melts was measured using a galvanic cell technique. By measuring the activity of oxygen in equilibrium with the molten metal and solid titanium oxide, in conjunction with the analysis of the samples for titanium, the activity coefficient of Ti was measured at 1873 K. Oxygen cells, comprised of a thoria-yttria electrolyte with a Cr-Cr2O3 reference electrode and an Al2O3 (ZrO2)-MO cermet tipped molybdenum lead wire, were used to take the electromotive force (EMF) measurements. The measured values of gamma(o)(Ti) and e(Ti)(Cr) were 0.018 and 0.1032, respectively.
引用
收藏
页码：537 / 541
页数：5
相关论文
共 50 条
  • [1] Activity of titanium in Fe-Cr melts
    H. Y. Choi
    W. E. Slye
    R. J. Fruehan
    R. C. Nunnington
    Metallurgical and Materials Transactions B, 2005, 36 : 537 - 541
  • [2] ULTRASONIC INVESTIGATION OF FE-CR MELTS
    KATS, YL
    SOKOLOV, LN
    OKOROKOV, GN
    RUSSIAN METALLURGY, 1978, (05): : 46 - 47
  • [3] THERMODYNAMICS OF FE-CR ALLOY MELTS
    VITUSEVICH, VT
    BILETSKII, AK
    SHUMIKHIN, VS
    RUSSIAN METALLURGY, 1987, (03): : 61 - 65
  • [4] Viscosity and supercooling of Fe-Cr (≤40 at % Cr) melts
    L. V. Kamaeva
    I. V. Sterkhova
    V. I. Lad’yanov
    Inorganic Materials, 2012, 48 : 318 - 324
  • [5] KINETICS OF NITROGEN ABSORPTION IN FE-CR MELTS
    CHO, WD
    RAO, YK
    JOURNAL OF METALS, 1987, 39 (10): : A54 - A54
  • [6] Thermodynamics of TiN formation in Fe-Cr melts
    Pak, JJ
    Jeong, YS
    Hong, IK
    Cha, WY
    Kim, DS
    Lee, YY
    ISIJ INTERNATIONAL, 2005, 45 (08) : 1106 - 1111
  • [7] Activities of carbon and nitrogen in Fe-Cr and Fe-Cr-Ni melts
    Ma, ZT
    Janke, D
    STEEL RESEARCH, 1999, 70 (12): : 491 - 495
  • [8] Activities of carbon and nitrogen in Fe-Cr and Fe-Cr-Ni melts
    Steel Res, 12 (491-495):
  • [9] NITROGEN SOLUBILITY IN FE-CR MELTS UNDER PRESSURE
    POMARIN, YM
    GRIGORENKO, GM
    LATASH, YV
    KANIBOLOTSKII, SA
    RUSSIAN METALLURGY, 1984, (06): : 7 - 11
  • [10] KINETICS OF NITROGEN DESORPTION FROM FE-CR MELTS
    RAO, YK
    CHO, WD
    JOURNAL OF METALS, 1988, 40 (11): : 30 - 30
12345