Synthesis of aza-analogues of poly(isothianaphthene)

被引：13
作者：
Huskic, M [1 ]
Vanderzande, D
Gelan, J
机构：
[1] Natl Inst Chem, Ljubljana 1000, Slovenia
[2] Univ Limburg, Div Chem, Inst Mat Res, B-3590 Diepenbeek, Belgium
来源：
SYNTHETIC METALS | 1999年 / 99卷 / 02期
关键词：
poly(thieno[3,4-b]pyridine); poly(thieno[3,4-c]pyridine); poly(thieno[3,4-b]pyrazine); polyisoindol; P4S10;
D O I：
10.1016/S0379-6779(98)01477-5
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The reaction of phthalic anhydride with phosphorus pentasulfide which gives poly(isothianaphthene) (PITN) has been extended to some other anhydrides and its derivatives (phthalimides and phthalhydrazide). The reaction with anhydrides leads to polymers, while the reaction with other derivatives can lead to thio, dithio compounds or polymers. Contrary to theoretical predictions, aza-analogues of PITN do not seem to have better electrical properties. The most conductive is polyisoindol with conductivity of 10(-4) S/cm, which is still 100 times lower than PITN synthesized under similar conditions. (C) 1999 Elsevier Science S.A. All rights reserved.
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收藏
页码：143 / 147
页数：5
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