Spontaneous assembly of a monolayer of charged gold nanocrystals at the water/oil interface

被引:420
|
作者
Reincke, F [1 ]
Hickey, SG [1 ]
Kegel, WK [1 ]
Vanmaekelbergh, D [1 ]
机构
[1] Univ Utrecht, Debye Inst, Vant Hoff Lab Phys & Colloid Chem, NL-3508 TA Utrecht, Netherlands
关键词
colloids; electrostatic interactions; interfaces; nanostructures; self-assembly;
D O I
10.1002/anie.200352339
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Charge control as a tool for assembly: Dense layers of individual, charged nanocrystals are formed at the aqueous/organic interface upon a slight reduction of the surface charge. The layers are remarkably robust, they creep up the glass (see picture). This method should be widely applicable to a broad range of charged colloids and will lead to the production of new materials.
引用
收藏
页码:458 / 462
页数:5
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