Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N′-di-3-propanoate ligands.: A structural evidence for geometry of hydrolytic product of some esters

被引：32
作者：
Sabo, TJ
Kaluderovic, GN
Grguric-Sipka, SR
Heinemann, FW
Trifunovic, SR
机构：
[1] Univ Belgrade, Fac Chem, YU-11001 Belgrade, Serbia And Mont, Serbia
[2] Univ Kragujevac, Fac Sci, Dept Chem, YU-34000 Kragujevac, Serbia And Mont, Serbia
[3] Inst Anorgan Chem 2, D-91058 Erlangen, Germany
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 02期
关键词：
platinum(IV); tetradentate ligands; bidentate ligands; eddp;
D O I：
10.1016/j.inoche.2003.11.007
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Depending on the ester alkyl group, the reaction of O,O-dialkylethylenediamine-N,N'-di-3-propanoate ligands (R(2)eddp) with potassium hexachloroplatinate(IV) afforded trans-dichloro(ethylenediamine-N,N'-di-3-propanoato)platinum(IV) and tetrachloro(O,O-dialkyl-ethylenediamine-N,N'-di-3-propanoato)platinum(IV) complexes. The complexes were characterized by elemental analysis, electronic absorption, infrared, H-1 and C-13 NMR spectroscopy. The trans configuration of [Pt(eddp)Cl-2] complex was confirmed by X-ray crystallography. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：241 / 244
页数：4
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