Effect of calcium chelators on physical changes in casein micelles in concentrated micellar casein solutions

被引:89
|
作者
de Kort, Esther [1 ]
Minor, Marcel [1 ]
Snoeren, Thom [1 ]
van Hooijdonk, Toon [2 ]
van der Linden, Erik [3 ]
机构
[1] Danone Res, Prod Dev Nutr Adv Med Nutr, Ctr Specialised Nutr, NL-6704 PH Wageningen, Netherlands
[2] Wageningen Univ, Dairy Sci & Technol Grp, NL-6703 HD Wageningen, Netherlands
[3] Wageningen Univ, Food Phys Grp, NL-6703 HD Wageningen, Netherlands
关键词
SKIM-MILK; PHYSICOCHEMICAL CHARACTERIZATION; EQUILIBRIA; VISCOSITY; TURBIDITY; GELATION; IONS; PRECIPITATION; DISSOCIATION; PHOSPHATES;
D O I
10.1016/j.idairyj.2011.06.007
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
The effect of calcium chelators on physical changes of casein micelles in concentrated micellar casein solutions was investigated by measuring calcium-ion activity, viscosity and turbidity, and performing ultracentrifugation. The highest viscosities were measured on addition of sodium hexametaphosphate (SHMP), because it cross-linked the caseins. For the weak calcium chelator disodium uridine monophosphate (Na2UMP), physical changes in the solutions were negligible. Disodium hydrogen phosphate (Na2HPO4), trisodium citrate (TSC), and sodium phytate (SP) caused similar increases in viscosity, but had different effects on turbidity. The increase in viscosity was attributed to swelling of the casein micelles (i.e., increased voluminosity) at decreasing calcium-ion activity. The major decrease in turbidity was due to dissociation of the casein micelles. The extent of micellar dissociation was dependent on the type and concentration of calcium chelator. It seems that the micelles were dissociated in the order of SHMP >= SP > TSC > Na2HPO4 > Na2UMP. (c) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:907 / 913
页数:7
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