Homogeneous Hydrogenations of Nitriles Catalyzed by Rhenium Complexes

被引：66
作者：
Rajesh, Kunjanpillai [1 ]
Dudle, Balz [1 ]
Blacque, Olivier [1 ]
Berke, Heinz [1 ]
机构：
[1] Univ Zurich, Inst Inorgan Chem, CH-8057 Zurich, Switzerland
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 09期
基金：
瑞士国家科学基金会;
关键词：
homogeneous hydrogenation; nitrile reduction; rhenium catalysts; secondary amines; triethylsilane; C-H BOND; SECONDARY-AMINES; MECHANISTIC ASPECTS; BITE ANGLE; REDUCTION; ACTIVATION; DINITRILES; PALLADIUM; CHEMICALS; ALDEHYDES;
D O I：
10.1002/adsc.201000867
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Rhenium(I) nitrosyl complexes bearing large bite angle diphosphines efficiently catalyze the hydrogenation of nitriles to the corresponding symmetrical secondary amines.
引用
收藏
页码：1479 / 1484
页数：6
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