Ni-nanoparticles usage for the reduction of ketones

被引:22
作者
Kidwai, Mazaahir [1 ]
Mishra, Neeraj Kumar [1 ]
Bansal, Vikas [1 ]
Kumar, Ajeet [2 ]
Mozumdar, Subho [2 ]
机构
[1] Univ Delhi, Dept Chem, Green Chem Res Lab, Delhi 110007, India
[2] Univ Delhi, Dept Chem, Lab Nanobiotechnol, Delhi 110007, India
关键词
Ni-nanoparticles; reduction; ammonium formate; hydrogen donor; hydrogen gas;
D O I
10.1016/j.catcom.2007.06.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ni-nanoparticles provide efficient catalyst for the reduction of aromatic and aliphatic ketones using ammonium formate or hydrogen (H-2) gas as hydrogen donor. Comparative studies were done on both hydrogen donors, i.e. ammonium formate and H, gas and it was found that ammonium formate was better than H, gas. This method devoid usage of metal oxide or toxic metals, which are required in excess amount. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:612 / 617
页数:6
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