Comparing the self-assembly processes of two redox-active exTTF-based regioisomer ligands

被引：4

作者：

Dekhtiarenko, Maksym ^{[1
,2
]}

Allain, Magali ^{[1
]}

Carre, Vincent ^{[3
]}

Aubriet, Frederic ^{[3
]}

Voitenko, Zoia ^{[2
]}

Salle, Marc ^{[1
]}

Goeb, Sebastien ^{[1
]}

机构：

[1] Univ Angers, MOLTECH Anjou, CNRS, 2 Bd Lavoisier, F-49045 Angers, France

[2] Taras Shevchenko Natl Univ Kyiv, 64-13 Volodymyrska St, UA-01033 Kiev, Ukraine

[3] Univ Lorraine, ICPM, FR 3624, LCP A2MC, 1 Bd Arago, F-57078 Metz 03, France

来源：

NEW JOURNAL OF CHEMISTRY | 2021年 / 45卷 / 45期

关键词：

HOST-GUEST INTERACTIONS; BINDING; RELEASE; COMPLEX; C-60;

D O I：

10.1039/d1nj04555e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of a new tetratopic extended-TTF (exTTF; 9,10-di(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene) ligand, bearing four pyridyl coordinating functions on the dihydroanthracenyl platform rather than on the 1,3-dithiol rings (previously described regioisomer), was reported. The self-assembly behaviors of both electroactive regioisomers were compared. While a M4L2 container was obtained with the previous one when reacted with the square planar Pd(dppf)OTf2 complex, the new ligand, when reacted under the same conditions, affords a M6L3 hexagonal structure that is composed of nine electro-active subunits that can be reversibly oxidized.

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页码：21015 / 21019

页数：5

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