A simple one-pot synthesis of β-alkoxy alcohols from alkenes

被引：12

作者：

Le Bras, J

Chatterjee, D

Muzart, J

机构：

[1] Univ Reims, CNRS, UMR React Select & Applicat, F-51687 Reims, France

[2] CMERI, Chem Sect, Durgapur 713209, India

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 28期

关键词：

Oxone((R)); beta-alkoxy alcohol; beta-hydroxy ether; one-pot synthesis; oxidation;

D O I：

10.1016/j.tetlet.2005.05.030

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

beta-Methoxy alcohols are easily obtained from the one-pot reaction of alkenes with oxone (R) in methanol, in the absence of any additive or catalyst. The use of other alcohols as solvents has shown that the efficiency of the process decreases with the steric hindrance of the alcohol. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：4741 / 4743

页数：3

共 21 条

[1] ANOMALOUS STERIC COURSE OF RING-OPENING REACTIONS OF INDENE OXIDE - RE-EXAMINATION [J].