An experimental investigation of the propagation mechanism of critical deflagration waves that lead to the onset of detonation

The reflection of a CJ detonation from a perforated plate is used to generate high speed deflagrations downstream in order to investigate the critical conditions that lead to the onset of detonation. Different perforated plates were used to control the turbulence in the downstream deflagration waves. Streak Schlieren photography, ionization probes and pressure transducers are used to monitor the flow field and the transition to detonation. Stoichiometric mixtures of acetylene-oxygen and propane-oxygen were tested at low initial pressures. In some cases, acetylene-oxygen was diluted with 80%, argon in order to render the mixture more "stable" (i.e., more regular detonation cell structure). The results show that prior to successful detonation initiation, a deflagration is formed that propagates at about half the CJ detonation velocity of the mixture. This "critical" deflagration (which propagates at a relatively constant velocity for a certain duration prior to the onset of detonation) is comprised of a leading shock wave followed by an extended turbulent reaction zone. The critical deflagration speed is not dependent on the turbulence characteristics of the perforated plate but rather on the energetics of the mixture like a CJ detonation (i.e., the deflagration front is driven by the expansion of the combustion products). Hence, the critical deflagration is identified as a CJ deflagration. The high intensity turbulence that is required to sustain its propagation is maintained via chemical instabilities in the reaction zone due to the coupling of pressure fluctuations with the energy release. Therefore, in "unstable" mixtures, critical deflagrations can be supported for long durations, whereas in "stable" mixtures, deflagrations decay as the initial plate generated turbulence decays. The eventual onset of detonation is postulated to be a result of the amplification of pressure waves (i.e., turbulence) that leads to the formation of local explosion centers via the SWACER mechanism during the pre-detonation period. (c) 2006 The Combustion Institute. Published by Elsevier Inc. All rights reserved.