Water quality assessment, multivariate analysis and human health risks of heavy metals in eight major lakes in Kenya

被引:79
作者
Githaiga, Kelvin Babu [1 ,2 ,3 ]
Njuguna, Samwel Maina [1 ,2 ,3 ]
Gituru, Robert Wahiti [4 ]
Yan, Xue [1 ,2 ]
机构
[1] Chinese Acad Sci, Key Lab Aquat Bot & Watershed Ecol, Wuhan Bot Garden, Wuhan 430074, Peoples R China
[2] Chinese Acad Sci, Sinoafr Joint Res Ctr, Wuhan 430074, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[4] Jomo Kenyatta Univ Agr & Technol, Dept Bot, POB 62000, Nairobi 00200, Kenya
基金
中国国家自然科学基金;
关键词
Heavy metals; Health risk assessment; Kenya lakes; Pollution evaluation; Water quality; DRINKING-WATER; INDEX; GROUNDWATER; RIVER; DISTRIBUTIONS; SEDIMENT; NAIVASHA; VICTORIA;
D O I
10.1016/j.jenvman.2021.113410
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study evaluates water quality, concentrations and health risks of heavy metals (HMs) in eight major lakes in Kenya namely Naivasha, Elementaita, Nakuru, Baringo, Bogoria, Turkana, Victoria and Magadi. Water quality was assessed using water quality index (WQI) and pollution evaluation index (PEI), while human health risk associated with ingestion and dermal contact of HMs was assessed using hazard quotients (HQ) and hazard index (HI). Principal component analysis (PCA) and hierarchical cluster analysis (HCA) were used to deduce the probable sources of the HMs. The average concentration of aluminium (Al), molybdenum (Mo), manganese (Mn), nickel (Ni), arsenic (As), zinc (Zn), selenium (Se), lead (Pb), chromium (Cr), mercury (Hg), cobalt (Co) and cadmium (Cd) in the eight lakes was 824.6, 66.1, 58.9, 16.2, 8.40, 7.84, 6.91, 4.65, 2.66, 0.86, 0.78 and 0.46, respectively, all in mu g/L. Al, Mn, As, and Mo were relatively high in Rift Valley lakes and exceeded the maximum permissible levels for drinking water. Notably, high HM concentrations were recorded at the entry points of rivers and areas with high human activities. Lake Magadi had the highest average WQI of 158.8 followed by lake Elementaita (128.4), Bogoria (79.5), Nakuru (73.3), Turkana (57.6), Victoria (52.3), Baringo (42.6) and Naivasha (25.5). Lake Magadi also had the highest average PEI of 40.0 followed by Elementaita (30.1), Bogoria (16.2), Nakuru (15.7), Victoria (10.8), Baringo (9.57), Turkana (9.53) and Naivasha (5.12). Based on WQI, Lake Naivasha water was excellent for drinking, Lake Victoria, Turkana, Baringo, Nakuru, and Bogoria had good water, but water from Lake Elementaita and Magadi was of poor quality. PEI classified the lakes as minimally polluted except Lake Magadi. Multivariate analysis concluded that Pb, Cr, Ni and Se had anthropogenic sources, mainly agricultural and urban runoff, but other HMs had natural influence. Although the HMs did not pose any health risks through dermal contact, HQingestion was >1 for adults and children consuming water from Lake Elementaita, Nakuru, Bogoria and Magadi due to non-carcinogenic risks associated with As, Zn and Mo. These results are important for formulating the necessary remediation policies to improve water quality in the eight lakes.
引用
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页数:11
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