Cadmium(II), manganese(II) and zinc(II) compounds

被引：11

作者：

Zhang, Rui-Feng ^{[1
,2
]}

Shi, Wei ^{[1
]}

Wang, Hong-Sheng ^{[1
]}

Cheng, Peng ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[2] Shanxi Normal Univ, Dept Chem, Linfen 041004, Shan Xi, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 10期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; crystal structure; in situ ligand synthesis;

D O I：

10.1080/00958970701609055

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new compounds, [Cd(mu(3)-Hpdh)(mu(2)-Cl)](n) (1), Mn(Hpdh)(2)(H2O)(2) (2) and Zn(Hpdh)(2) (H2O)(2) (3) (H(2)pdh =pyridine-2,3-dicarbo-2,3-hydrazide), have been synthesized and characterized by elemental analysis, IR spectra, TG and single-crystal X-ray diffraction. Under hydrothermal conditions, H(2)pdh is generated by an in situ acylation of H(2)pda (H(2)pda =pyridine-2,3-dicarboxylic acid) with hydrazine hydrate. Complex 1 features a 2D layer structure constructed by a dinuclear Cd(II) building block. In complexes 2 and 3, hydrogen bonding interactions connect mononuclear structures into 3D supramolecular frameworks.

引用

页码：1606 / 1614

页数：9

共 21 条

[1] In situ ligand synthesis and construction of an unprecedented three-dimensional array with silver(I): a new approach to inorganic crystal engineering [J].

Blake, AJ ;

Champness, NR ;

Chung, SSM ;

Li, WS ;

Schroder, M .

CHEMICAL COMMUNICATIONS, 1997, (17) :1675-1676

[2] Solvothermal in situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry [J].

Chen, Xiao-Ming ;

Tong, Ming-Liang .

ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (02) :162-170

[3] Crystal engineering of NLO materials based on metal-organic coordination networks [J].

Evans, OR ;

Lin, WB .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522

[4] A supramolecular approach to an allosteric catalyst [J].

Gianneschi, NC ;

Bertin, PA ;

Nguyen, ST ;

Mirkin, CA ;

Zakharov, LN ;

Rheingold, AL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (35) :10508-10509

[5] One- and three-dimensional coordination polymers containing organic ligands produced through in situ hydrothermal reactions [J].

Hu, XX ;

Pan, CL ;

Xu, JQ ;

Cui, XB ;

Yang, GD ;

Wang, TG .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (07) :1566-1569

[6] Metal-organic frameworks [J].

James, SL .

CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) :276-288

[7] A critical account on π-π stacking in metal complexes with aromatic nitrogen-containing ligands [J].

Janiak, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (21) :3885-3896

[8] Engineering coordination polymers towards applications [J].

Janiak, C .

DALTON TRANSACTIONS, 2003, (14) :2781-2804

[9] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[10] Cucurbituril homologues and derivatives: New opportunities in supramolecular chemistry [J].

Lee, JW ;

Samal, S ;

Selvapalam, N ;

Kim, HJ ;

Kim, K .

ACCOUNTS OF CHEMICAL RESEARCH, 2003, 36 (08) :621-630

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