Conductivity Studies on Li1-xAlxTi2-x(PO4)3 (X=0.0-0.5) Due to the Addition of Al3+ Trivalent Cation

被引:0
作者
Hamidi, Maziidah [1 ]
Mohamed, Syafawati Nadiah [1 ]
Yahya, M. Z. A. [1 ]
机构
[1] Univ Teknol MARA, Fac Sci Appl, Shah Alam 40450, Selangor, Malaysia
来源
MATERIALS PROCESSING TECHNOLOGY, PTS 1-3 | 2012年 / 418-420卷
关键词
glass ceramic; LATP; NASICON-type; EIS; GLASS-CERAMICS; ELECTRICAL-PROPERTIES; LITHIUM; PECULIARITIES; TRANSPORT;
D O I
10.4028/www.scientific.net/AMR.418-420.1869
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The Li-ion fast conductor, Li1-xAlxTi2-x(PO4)(3) (LATP) compound were synthesized by a sol-gel method. Effects due to the addition of Al3+ into Li1-xAlxTi2-x(PO4)(3) (x=0.0-0.5) glass-ceramics system have been investigated using electrochemical impedance spectroscopy (EIS), X-ray differential analysis (XRD) and permittivity studies. The crystalline phase of the samples obtained confirming that they had a characteristic of glass-ceramics structure.
引用
收藏
页码:1869 / 1872
页数:4
相关论文
共 17 条
  • [1] On the structure of Li3Ti2(PO4)3
    Aatiq, A
    Ménétrier, M
    Croguennec, L
    Suard, E
    Delmas, C
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (10) : 2971 - 2978
  • [2] Stoichiometric changes in lithium conducting materials based on Li1+xAlxTi2-x(PO4)3:: impedance, X-ray and NMR studies
    Best, AS
    Forsyth, M
    MacFarlane, DR
    [J]. SOLID STATE IONICS, 2000, 136 : 339 - 344
  • [4] POROUS GLASS-CERAMICS COMPOSED OF A TITANIUM PHOSPHATE CRYSTAL SKELETON - A REVIEW
    HOSONO, H
    ABE, Y
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1995, 190 (03) : 185 - 197
  • [5] Electrical properties of Li1.3Ge1.4Ti0.3Al0.3(PO4)3 superionic ceramics
    Kazakevicius, E.
    Urcinskas, A.
    Kezionis, A.
    Dindune, A.
    Kanepe, Z.
    Ronis, J.
    [J]. ELECTROCHIMICA ACTA, 2006, 51 (27) : 6199 - 6202
  • [6] Transport studies on filler-doped chitosan based polymer electrolyte
    Majid, SR
    Idris, NH
    Hassan, MF
    Winie, T
    Khiar, ASA
    Arof, AK
    [J]. IONICS, 2005, 11 (5-6) : 451 - 455
  • [7] Lithium and potassium ion conduction in A3TiB′P3O12 (A=Li, K; B′=Zn, Cd) NASICON-type glasses
    Mariappan, CR
    Govindaraj, G
    Roling, B
    [J]. SOLID STATE IONICS, 2005, 176 (7-8) : 723 - 729
  • [8] Recent progress of glass and glass-ceramics as solid electrolytes for lithium secondary batteries
    Minami, Tsutomu
    Hayashi, Akitoshi
    Tatsumisago, Masahiro
    [J]. SOLID STATE IONICS, 2006, 177 (26-32) : 2715 - 2720
  • [9] Electrochemical studies on epoxidised natural rubber-based gel polymer electrolytes for lithium-air cells
    Mohamed, S. N.
    Johari, N. A.
    Ali, A. M. M.
    Harun, M. K.
    Yahya, M. Z. A.
    [J]. JOURNAL OF POWER SOURCES, 2008, 183 (01) : 351 - 354
  • [10] Semi sol-gel synthesis, conductivity and luminescence studies of Ca0.5Fe1-xEuxSb(PO4)3 (x=0.1, 0.15 and 0.2)
    Navulla, Anantharamulu
    [J]. SOLID STATE IONICS, 2010, 181 (13-14) : 659 - 663