The Sorption Performance of Cetyl Trimethyl Ammonium Bromide-Capped La0.9Sr0.1FeO3 Perovskite for Organic Pollutants from Industrial Processes

被引:6
作者
Ali, Shimaa M. [1 ,2 ]
Eskandrani, Areej A. [2 ]
机构
[1] Cairo Univ, Chem Dept, Fac Sci, Giza 12613, Egypt
[2] Taibah Univ, Chem Dept, Fac Sci, Medinah 30002, Saudi Arabia
来源
MOLECULES | 2020年 / 25卷 / 07期
关键词
Ternary perovskites; surfactant; capping; adsorption; Congo red dye; water decontamination; METAL IONS REMOVAL; CONGO RED; ELECTROCHEMICAL SENSOR; CATALYTIC-ACTIVITY; AQUEOUS-SOLUTIONS; ADSORPTION; NANOPARTICLES; SURFACTANTS; FABRICATION; COMPOSITES;
D O I
10.3390/molecules25071640
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
La0.9Sr0.1FeO3 perovskite, prepared by the microwave-assisted method, was capped with cetyl trimethyl ammonium bromide (CTAB) cationic surfactant, and applied as a sorbent for the removal of the anionic Congo red (CR) dye from aqueous solutions. X-ray diffraction (XRD) patterns showed that the perovskite structure was not affected by capping; however, the particle size increased. There was a hipsochromic shift in the value of lambda(max) of the CR absorption spectrum in the presence of CTAB, which indicated the formation of an oppositely charged dye-surfactant complex. The adsorption efficiency of CTAB-capped La0.9Sr0.1FeO3 was independent of the pH of the solution-equilibrium was reached after a few minutes. The value of the maximum adsorption capacity, q(m), was 151.52 mgg(-1), which was 10-times higher than that of the pure perovskite. The proposed sorbent maintained its excellent sorption ability in the presence of the sample matrix; therefore, it can be regenerated and reused with unchanged performance.
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页数:15
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