Hydrogen bonding in coordinated thiosemicarbazones:: ammine[2-hydroxy-1-naphthaldehyde 4-methylthiosemicarbazonato]nickel(II)

被引：2

作者：

Martínez, JV ^{[1
]}

Hernández-Ortega, S ^{[1
]}

Jimenez, VB ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536803027971

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Ni(C13H11N3OS)(NH3)], the Ni atom is four-coordinate, with a distorted square-planar geometry. The 2-hydroxy-1-naphthaldehyde 4-methylthiosemicarbazonate ligand coordinates in a tridentate manner through the S, imine-N and O atoms, the ammonia molecule completing the coordination. The molecules are connected by N-H...N hydrogen bonds, through c-glide-plane translations, forming extended chains.

引用

页码：M42 / M44

页数：3

共 8 条

[1]

Barbour L.J., 2001, J SUPRAMOL CHEM, V1, P189

[2] AMINE(SALICYLALDEHYDE THIOSEMICARBAZONATO)NICKEL(II) [J].

GYEPES, E ;

GLOWIAK, T .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1989, 45 :391-392

[3] Copper(II) and nickel(II) complexes of 5-methyl-2-hydroxyacetophenone N(4)-substituted thiosemicarbazones [J].

Labisbal, E ;

Haslow, KD ;

Sousa-Pedrares, A ;

Valdés-Martínez, J ;

Hernández-Ortega, S ;

West, DX .

POLYHEDRON, 2003, 22 (20) :2831-2837

[4]

Sheldrick G.M., 1997, SHELXTL VERSION 5 1

[5]

Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930]

[6]

*SIEM AN XRAY INST, 1994, XSCANS VERS 2 1

[7] STRUCTURE OF AMMINE[SALICYLALDEHYDE 4-PHENYLTHIOSEMICARBAZONATO(2-)]NICKEL(II), [NI(C14H11N3OS)(NH3)] [J].

SORIANOGARCIA, M ;

TOSCANO, RA ;

VALDESMARTINEZ, J ;

FERNANDEZ, JM .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 (APR) :498-500

[8] Ammine[2-hydroxy-1-naphthaldehyde 4-piperidylthiosemicarbazonato]nickel(II) [J].

Valdés-Martínez, J ;

Hernández-Ortega, S ;

Jimenez, VB .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 :M710-M711

← 1 →