Selective hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over cobalt nanoparticle inlaid cobalt phyllosilicate

被引：8
作者：
Sun, Lixia [1 ]
Li, Shangyang [1 ]
Gao, Zhuoyou [1 ]
Gao, Shutao [1 ]
Gao, Wei [1 ]
Cheng, Xiang [1 ]
Shang, Ningzhao [1 ]
Gao, Yongjun [2 ]
Wang, Chun [1 ]
机构：
[1] Hebei Agr Univ, Coll Sci, Baoding 071001, Peoples R China
[2] Hebei Univ, Coll Chem & Environm Sci, Baoding 071000, Peoples R China
来源：
DALTON TRANSACTIONS | 2022年 / 51卷 / 08期
基金：
中国国家自然科学基金;
关键词：
POT MULTICOMPONENT SYNTHESIS; HETEROGENEOUS NANOCATALYST; BIMETALLIC CATALYST; DIMETHYL OXALATE; HIGH-PERFORMANCE; EFFICIENT; HYDROGENATION; CARBON; OXIDE; ACID;
D O I：
10.1039/d1dt03992j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Fabrication of biofuels and chemicals from renewable biomass is highly desirable to replace petrochemicals. Hydrogenolysis of biomass derived 5-hydroxymethylfurfural (HMF) is a promising way to obtain furanic fuels. In this paper, we describe the preparation of a CoSi-PS catalyst derived from cobalt phyllosilicate using a silica sol as the silica source. CoSi-PS exhibited excellent catalytic performance for the hydrogenolysis reaction of HMF to produce liquid 2,5-dimethylfuran (DMF) biofuel. 100% conversion of HMF and 97.5% selectivity for DMF were achieved at 170 degrees C and 1.5 MPa H-2 for 4 h, which was superior to most of the reported catalysts. The excellent performance can be attributed to the strong interactions between the metal and support, highly dispersed cobalt nanoparticles and the Lewis acid sites induced by the coordinated unsaturated Co(ii) sites in phyllosilicate.
引用
收藏
页码：3096 / 3103
页数：8
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