Controlled radical polymerization of styrene in miniemulsion polymerization using reversible addition fragmentation chain transfer

被引：22
|
作者：
Uzulina, I
Gaillard, N
Guyot, A
Claverie, K
机构：
[1] Univ New Hampshire, Durham, NH 03824 USA
[2] Latvian State Univ, Fac Chem, LV-1586 Riga, Latvia
[3] CNRS, CPE, Lab LCPP, F-69616 Villeurbanne, France
来源：
COMPTES RENDUS CHIMIE | 2003年 / 6卷 / 11-12期
关键词：
polymerization; radical; living; emulsion; styrene; nucleation;
D O I：
10.1016/j.crci.2003.10.004
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Miniemulsion polymerizations of styrene in the presence of two reversible addition-fragmentation chain-transfer (RAFT) agents were studied. The rates were significantly retarded by the presence of a RAFT agents S-(thiobenzoyl)thioglycolic acid, 1, or dithiobenzoic acid 1-phenylethyl ester, 2. Control in miniemulsion polymerization is not as good as for bulk polymerizations. The miniemulsions could also be stabilized against Ostwald ripening by a polymer terminated by a dithiobenzoic moiety. In this case. the polymerization was not controlled because of the generation of renucleated particles.
引用
收藏
页码：1375 / 1384
页数：10
相关论文
共 50 条
  • [1] Living radical polymerization in miniemulsion using reversible addition-fragmentation chain transfer
    de Brouwer, H
    Tsavalas, JG
    Schork, FJ
    Monteiro, MJ
    MACROMOLECULES, 2000, 33 (25) : 9239 - 9246
  • [2] Miniemulsion reversible addition fragmentation chain transfer polymerization of vinyl acetate
    Russum, JP
    Barbre, ND
    Jones, CW
    Schork, FJ
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (10) : 2188 - +
  • [3] Controlled radical polymerization of a trialkylsilyl methacrylate by reversible addition-fragmentation chain transfer polymerization
    Nguyen, MN
    Bressy, C
    Margaillan, A
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (22) : 5680 - 5689
  • [4] Reversible addition fragmentation transfer (RAFT) polymerization of styrene in a miniemulsion: A mechanistic investigation
    Yang, L
    Luo, YW
    Li, BG
    POLYMER, 2006, 47 (02) : 751 - 762
  • [5] Controlled radical polymerization of styrene mediated by dithiobenzoates as reversible addition-fragmentation chain-transfer agents
    Chernikova, E. V.
    Tarasenko, A. V.
    Garina, E. S.
    Golubev, V. B.
    POLYMER SCIENCE SERIES A, 2006, 48 (10) : 1046 - 1057
  • [6] Controlled radical polymerization of styrene mediated by dithiobenzoates as reversible addition-fragmentation chain-transfer agents
    E. V. Chernikova
    A. V. Tarasenko
    E. S. Garina
    V. B. Golubev
    Polymer Science Series A, 2006, 48
  • [7] Mechanism and kinetics of RAFT (reversible addition-fragmentation chain transfer)-based controlled radical polymerization of styrene
    Goto, Atsushi
    Sato, Koich
    Fukuda, Takeshi
    Mood, Graeme
    Rizzardo, Eva
    Thong, San H.
    American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, 1999, 40 (02): : 397 - 398
  • [8] Reversible addition-fragmentation transfer miniemulsion polymerization of styrene induced by γ-ray irradiation
    Zhou, Guangtian
    Ma, Yi
    CHEMISTRY LETTERS, 2008, 37 (08) : 850 - 851
  • [9] Reversible addition fragmentation chain transfer mediated dispersion polymerization of styrene
    Saikia, Prakash J.
    Lee, Jung Min
    Lee, Byung H.
    Choe, Soonja
    MACROMOLECULAR SYMPOSIA, 2007, 248 : 249 - 258
  • [10] Kinetics of styrene reversible addition-fragmentation chain transfer polymerization
    Wang, Zhenxi
    Zhang, Qinghua
    Zhan, Xiaoli
    Chen, Fengqiu
    Xiong, Jihai
    Huagong Xuebao/CIESC Journal, 2010, 61 (04): : 854 - 860
12345