Synthesis of Cyclic and Heterocyclic Compounds via Gold-Catalyzed Reactions

被引：19

作者：

Wang, Qiang ^{[1
]}

Shi, Min ^{[1
]}

机构：

[1] Univ Chinese Acad Sci, Shanghai Inst Organ Chem, Chinese Acad Sci, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

来源：

SYNLETT | 2017年 / 28卷 / 17期

基金：

中国国家自然科学基金;

关键词：

gold catalysis; cycloisomerization; propargylic esters; Au(I); Au(III) redox catalysis; VISIBLE-LIGHT PHOTOREDOX; PROPARGYLIC ESTERS; GOLD(I)-CATALYZED CYCLOISOMERIZATION; MOLECULAR COMPLEXITY; DERIVATIVES; FLUORINATION; SELECTFLUOR; CARBENES; KETONES; ALKYNES;

D O I：

10.1055/s-0036-1590827

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This account outlines the latest advances from our group in the field of gold catalysis. A variety of cyclic and heterocyclic compounds, containing different sized skeletons, are synthesized selectively by fine-tuning the substrates, catalysts, and ligands. Au(I)/Au(III) redox catalysis is applied in our latest work through adding external oxidation. The reaction mechanisms are discussed in detail. Moreover, the photoredox catalytic process is also introduced briefly, which opens avenues for the development of new strategies in gold chemistry.

引用

页码：2230 / 2240

页数：11

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