Exo-metal coordination by a tricyclic [{P(μ-N-2-NC5H4)}2(μ-O)]2 dimer in [{P(μ-N-2-NC5H4)}2(μ-O)]2{CuCl•(C5H5N)2}4 {2-NC5H4=2-pyridyl, C5H5N=pyridine)

被引:28
|
作者
Bond, AD
Doyle, EL
García, F
Kowenicki, RA
McPartlin, M
Riera, L
Wright, DS
机构
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
[2] Univ N London, Sch Chem, London N7 8DB, England
关键词
D O I
10.1039/b309842g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The in situ reaction of the phosphazane dimer [ClP(mu-N-2-NC5H4)](2) (2) with CuCl in the presence Of C5H5N/H2O gives the title complex [{P(mu-N-2-NC5H4)}(2)(mu-O)](2)(CuCl.(C5H5N)(2))(4) (1), containing a tricyclic [(P(mu-N-2-NC5H4)}2(mu-O)](2) ligand which is isoelectronic with species of the type [{P(mu-NR))(2)NR](2).
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页码:2990 / 2991
页数:2
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