Novel Environmentally Friendly Inorganic Orange Pigments Based on Ca14Al10Zn6O35

被引：4
|
作者：
Oka, Ryohei [1 ]
Kosaya, Takashi [1 ]
Masui, Toshiyuki [1 ]
机构：
[1] Tottori Univ, Grad Sch Engn, Ctr Res Green Sustainable Chem, Dept Chem & Biotechnol, 4-101 Koyama Cho Minami, Tottori 6808552, Japan
来源：
CHEMISTRY LETTERS | 2018年 / 47卷 / 12期
基金：
日本学术振兴会;
关键词：
Environmentally friendly; Inorganic orange pigments; Optical properties; THERMAL SYNTHESIS; SOLID-SOLUTIONS; FE3+;
D O I：
10.1246/cl.180744
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel environmentally friendly inorganic orange pigments based on Ca-14(Al1-xFex)(10)Zn6O35 (0 <= x <= 0.30) were synthesized using a solid-state reaction method. The Fe3+-doped samples strongly absorbed visible light at wavelengths from 380 to 490 nm due to the d-d ((6)A(1) -> E-4) transition of Fe3+. In addition, the optical absorption around 600 nm, corresponding to the (6)A(1) -> T-4(2) transition of Fe3+, also increased with increasing the Fe3+ concentration. The sample color gradually turned from yellow to orange as the Fe3+ content increased.
引用
收藏
页码：1522 / 1525
页数：4
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