First synthesis of a new fullerene oximes bis(9-[hydroxo]-1-[1′-hydroxymino-2′-oxo-2′-alkyl-ethyl])1,9-dihydro-[C60-Ih][5,6]fullerenes via reaction of C60 with ketones and NaNO2 promoted by HCl

被引：1

作者：

Bulgakov, Ramil G. ^{[1
]}

Kinzyabaeva, Zemfira S. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochem & Catalysis, 141 Pr Oktyabrya, Ufa 450075, Russia

来源：

FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES | 2016年 / 24卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

fullerene C-60; nitrosation; oximes; ketones; BISADDUCTS; DERIVATIVES;

D O I：

10.1080/1536383X.2016.1174697

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A mixture of cis-2 and cis-3 isomers of new fullerene derivatives bis(9-[hydroxo]-1-[1'-hydroxymino-2'-oxo2'- alkyl-ethyl])-1,9-dihydro-[C-60-I-h][5,6]fullerenes have been selectively synthesized with high yields at the reaction of C-60 fullerene with ketones Me2CO, EtMeCO, i-PrMeCO, PhMeCO in the presence of NaNO2 and HCl.

引用

页码：441 / 445

页数：5

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