First synthesis of a new fullerene oximes bis(9-[hydroxo]-1-[1′-hydroxymino-2′-oxo-2′-alkyl-ethyl])1,9-dihydro-[C60-Ih][5,6]fullerenes via reaction of C60 with ketones and NaNO2 promoted by HCl

被引:1
作者
Bulgakov, Ramil G. [1 ]
Kinzyabaeva, Zemfira S. [1 ]
机构
[1] Russian Acad Sci, Inst Petrochem & Catalysis, 141 Pr Oktyabrya, Ufa 450075, Russia
基金
俄罗斯基础研究基金会;
关键词
fullerene C-60; nitrosation; oximes; ketones; BISADDUCTS; DERIVATIVES;
D O I
10.1080/1536383X.2016.1174697
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A mixture of cis-2 and cis-3 isomers of new fullerene derivatives bis(9-[hydroxo]-1-[1'-hydroxymino-2'-oxo2'- alkyl-ethyl])-1,9-dihydro-[C-60-I-h][5,6]fullerenes have been selectively synthesized with high yields at the reaction of C-60 fullerene with ketones Me2CO, EtMeCO, i-PrMeCO, PhMeCO in the presence of NaNO2 and HCl.
引用
收藏
页码:441 / 445
页数:5
相关论文
共 16 条
  • [1] Versatile synthesis of oligosaccharide-containing fullerenes
    Abe, S
    Moriyama, H
    Niikura, K
    Fei, F
    Monde, K
    Nishimura, S
    [J]. TETRAHEDRON-ASYMMETRY, 2005, 16 (01) : 15 - 19
  • [2] [Anonymous], 2005, FULLERENES
  • [3] Additions of azomethine ylides to fullerene C60 assisted by a removable anchor
    Da Ros, T
    Prato, M
    Lucchini, V
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (14) : 4289 - 4297
  • [4] Gordon A. J., 1972, HDB PRACTICAL DATA T
  • [5] Hirsch A., 1994, CHEM FULLERENES
  • [6] Isolation and characterization of all eight bisadducts of fulleropyrrolidine derivatives
    Kordatos, K
    Bosi, S
    Da Ros, T
    Zambon, A
    Lucchini, V
    Prato, M
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (08) : 2802 - 2808
  • [7] Separation and characterization of [60]fullerene bisadducts modified by 4,5-dimethoxy-o-quinodimethane
    Nakamura, Y
    O-Kawa, K
    Matsumoto, M
    Nishimura, J
    [J]. TETRAHEDRON, 2000, 56 (30) : 5429 - 5434
  • [8] Neyland O. Ya., 1990, ORGANIC CHEM
  • [9] Unusual redox-type addition of nitroalkanes on the C60 surface
    Ohno, M
    Yashiro, A
    Tsunenishi, Y
    Eguehi, S
    [J]. CHEMICAL COMMUNICATIONS, 1999, (09) : 827 - 828
  • [10] Piotrovsky L. B., 2006, FULLERENES BIOL