The effect of silica availability on the mechanism of geopolymerisation

被引：216

作者：

Hajimohammadi, Ailar ^{[1
]}

Provis, John L. ^{[1
]}

van Deventer, Jannie S. J. ^{[1
,2
]}

机构：

[1] Univ Melbourne, Dept Chem & Biomol Engn, Melbourne, Vic 3010, Australia

[2] Zeobond Pty Ltd, Somerton, Vic 3062, Australia

来源：

CEMENT AND CONCRETE RESEARCH | 2011年 / 41卷 / 03期

基金：

澳大利亚研究理事会;

关键词：

Alkali activated cement; Kinetics; Reaction; Nucleation; Characterization; FLY-ASH; GEL FORMATION; SODIUM ALUMINATE; FTIR; MICROSTRUCTURE; MICROANALYSIS; TECHNOLOGY; ACTIVATION; MICROSCOPY; CHEMISTRY;

D O I：

10.1016/j.cemconres.2011.02.001

中图分类号：

TU [建筑科学];

学科分类号：

0813 ;

摘要：

The effect of silica availability on geopolymer binder formation is investigated in the geothermal silica-sodium aluminate-water system, using sodium silicate solution as an additional, highly available silica source. Time-resolved and spatially-resolved FTIR data are combined to provide a mechanistic understanding of the role of silica availability in controlling geopolymer nucleation and gel growth behaviour. A higher degree of alumina contribution to geopolymer gels and newly formed crystal phases is observed in systems with higher silica availability. Gel nucleation is observed to take place in the region immediately surrounding the solid silica source particles when no dissolved silica is initially supplied. Conversely, mixes which initially contain dissolved silica show nucleation in bulk regions, and involving more of the Al which is rapidly released from the sodium aluminate precursor. These differences in nucleation lead to a more chemically heterogeneous binder in the case where silica is released more gradually. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：210 / 216

页数：7

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