Nickel and palladium catalyzed Kumada-Tamao-Corriu cross-coupling reactions: scope and recent advances

被引：5
|
作者：
Dahadha, Adnan A. [1 ]
Aldhoun, Mohammad M. [2 ]
机构：
[1] Philadelphia Univ, Fac Sci, Biotechnol Dept, POB 19392, Amman, Jordan
[2] Philadelphia Univ, Fac Pharm, POB 19392, Amman, Jordan
来源：
ARKIVOC | 2018年
关键词：
Kumada coupling; nickel catalysis; palladium catalysis; Grignard reagents; biaryls; FUNCTIONALIZED GRIGNARD-REAGENTS; NONACTIVATED ALKYL-HALIDES; ARYL CHLORIDES; EXCHANGE-REACTION; KETONE SYNTHESIS; BOND ACTIVATION; ORGANIC HALIDES; HETEROARYL; PD; ORGANOZINC;
D O I：
10.24820/ark.5550190.p010.746
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The nickel and palladium catalyzed Kumada-Tamao-Corriu cross-coupling reaction is a powerful method for the formation of carbon-carbon bonds, employed in many large-scale applications in the pharmaceutical and electronic material industries. Kumada cross-coupling is the reaction of an organohalide substrate with a Grignard reagent to produce the corresponding coupled product using a palladium or nickel catalyst. This review covers key developments in Kumada cross-coupling reactions over the past ten years. [GRAPHICS]
引用
收藏
页码：234 / 253
页数：20
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