Racemic 2-isopropyl-3-(2-nitrob-enzyl)-1,3-thiazolidin-4-one crystallizes in the space group P212121 with Z′=2:: two different interpenetrating three-dimensional frameworks formed by C-H•••O hydrogen bond

被引:7
作者
Cunico, Wilson
Gomes, Claudia R. B.
Warden, Solange M. S. V.
Low, John N.
Glidewell, Christopher
机构
[1] Fiocruz MS, Inst Tecnol & Farm, BR-21041250 Rio De Janeiro, RJ, Brazil
[2] Univ Aberdeen, Dept Chem, Aberdeen, Scotland
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2007年 / 63卷 / 07期
关键词
14;
D O I
10.1107/S0108270107022913
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
rac-2-Isopropyl-3-(2-nitrobenzyl)-1,3-thiadiazolin-4-one, C13H16N2O3S, is a rare example of a racemate crystallizing in the space group P2(1)2(1)2(1), with one molecule each of S and R configurations, whose conformations are almost mirror images, within the asymmetric unit. The molecules of S configuration are linked by two C-H center dot center dot center dot O hydrogen bonds into a three-dimensional framework, and the molecules of R configuration are linked by two further C-H center dot center dot center dot O hydrogen bonds into a different type of three-dimensional framework; the two frameworks are linked by a fifth C-H center dot center dot center dot O hydrogen bond.
引用
收藏
页码:O411 / O414
页数:4
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